Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate

In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa­hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni—N bond distances range from 2.1061 (18) to...

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Detalles Bibliográficos
Autores principales: Jun, Qian, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980088/
https://www.ncbi.nlm.nih.gov/pubmed/21579925
http://dx.doi.org/10.1107/S1600536809051964
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author Jun, Qian
Zhang, Chi
author_facet Jun, Qian
Zhang, Chi
author_sort Jun, Qian
collection PubMed
description In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa­hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni—N bond distances range from 2.1061 (18) to 2.1425 (18) Å. The Mo—C and C—N distances in the [Mo(CN)(8)] unit range from 2.154 (2) to 2.174 (2) Å and 1.149 (3) to 1.156 (3) Å, respectively. The complex ions and water mol­ecules are linked by weak N—H⋯N/O and O—H⋯N/O hydrogen bonds into a three-demensional structure.
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spelling pubmed-29800882010-12-30 Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate Jun, Qian Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(2)H(8)N(2))(3)](2)[Mo(CN)(8)]·5H(2)O, the Ni(II) ion is coordinated by six N atoms from three ethane-1,2-diamine ligands in a distorted octa­hedral geometry, while the Mo(IV) atom is coordianted by eight cyanide ligands. The Ni—N bond distances range from 2.1061 (18) to 2.1425 (18) Å. The Mo—C and C—N distances in the [Mo(CN)(8)] unit range from 2.154 (2) to 2.174 (2) Å and 1.149 (3) to 1.156 (3) Å, respectively. The complex ions and water mol­ecules are linked by weak N—H⋯N/O and O—H⋯N/O hydrogen bonds into a three-demensional structure. International Union of Crystallography 2009-12-09 /pmc/articles/PMC2980088/ /pubmed/21579925 http://dx.doi.org/10.1107/S1600536809051964 Text en © Jun and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jun, Qian
Zhang, Chi
Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title_full Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title_fullStr Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title_full_unstemmed Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title_short Bis[tris­(ethane-1,2-diamine)nickel(II)] octa­cyanidomolybdate(IV) penta­hydrate
title_sort bis[tris­(ethane-1,2-diamine)nickel(ii)] octa­cyanidomolybdate(iv) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980088/
https://www.ncbi.nlm.nih.gov/pubmed/21579925
http://dx.doi.org/10.1107/S1600536809051964
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