Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)

In the title complex, [PtI(2)(C(12)H(8)N(2))], the Pt(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar mol­ecules, with a maximum deviation of 0.170 (3) Å from the least-squ...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980094/
https://www.ncbi.nlm.nih.gov/pubmed/21579960
http://dx.doi.org/10.1107/S1600536809053100
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PtI(2)(C(12)H(8)N(2))], the Pt(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar mol­ecules, with a maximum deviation of 0.170 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pt⋯Pt distance of 4.8510 (6) Å. In the column, π–π inter­actions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.703 (5) Å.
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spelling pubmed-29800942010-12-30 Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtI(2)(C(12)H(8)N(2))], the Pt(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar mol­ecules, with a maximum deviation of 0.170 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pt⋯Pt distance of 4.8510 (6) Å. In the column, π–π inter­actions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.703 (5) Å. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980094/ /pubmed/21579960 http://dx.doi.org/10.1107/S1600536809053100 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title_full Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title_fullStr Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title_full_unstemmed Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title_short Diiodido(1,10-phenanthroline-κ(2) N,N′)platinum(II)
title_sort diiodido(1,10-phenanthroline-κ(2) n,n′)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980094/
https://www.ncbi.nlm.nih.gov/pubmed/21579960
http://dx.doi.org/10.1107/S1600536809053100
work_keys_str_mv AT hakwang diiodido110phenanthrolinek2nnplatinumii

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