Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate

There are two 5-amino-1,3,4-thia­diazole-2(3H)-thiolate anions in the asymmetric unit of the title compound, Na(+)·C(2)H(2)N(3)S(2) (−)·2H(2)O, which are almost perpendicular to each other [dihedral angle = 84.64 (6)°]. The two Na(+) cations are in distorted fourfold coordinations by O atoms of the...

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Detalles Bibliográficos
Autores principales: Wu, Jiayi, Wang, Yifeng, Yi, Guo, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980096/
https://www.ncbi.nlm.nih.gov/pubmed/21579921
http://dx.doi.org/10.1107/S1600536809051897
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author Wu, Jiayi
Wang, Yifeng
Yi, Guo
Luo, Shuping
author_facet Wu, Jiayi
Wang, Yifeng
Yi, Guo
Luo, Shuping
author_sort Wu, Jiayi
collection PubMed
description There are two 5-amino-1,3,4-thia­diazole-2(3H)-thiolate anions in the asymmetric unit of the title compound, Na(+)·C(2)H(2)N(3)S(2) (−)·2H(2)O, which are almost perpendicular to each other [dihedral angle = 84.64 (6)°]. The two Na(+) cations are in distorted fourfold coordinations by O atoms of the water molecules. The crystal structure is stabilized by N—H⋯S, O—H⋯N and O—H⋯S hydrogen bonds.
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spelling pubmed-29800962010-12-30 Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate Wu, Jiayi Wang, Yifeng Yi, Guo Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two 5-amino-1,3,4-thia­diazole-2(3H)-thiolate anions in the asymmetric unit of the title compound, Na(+)·C(2)H(2)N(3)S(2) (−)·2H(2)O, which are almost perpendicular to each other [dihedral angle = 84.64 (6)°]. The two Na(+) cations are in distorted fourfold coordinations by O atoms of the water molecules. The crystal structure is stabilized by N—H⋯S, O—H⋯N and O—H⋯S hydrogen bonds. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980096/ /pubmed/21579921 http://dx.doi.org/10.1107/S1600536809051897 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Jiayi
Wang, Yifeng
Yi, Guo
Luo, Shuping
Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title_full Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title_fullStr Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title_full_unstemmed Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title_short Sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
title_sort sodium 5-amino-1,3,4-thia­diazole-2-thiol­ate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980096/
https://www.ncbi.nlm.nih.gov/pubmed/21579921
http://dx.doi.org/10.1107/S1600536809051897
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AT wangyifeng sodium5amino134thiadiazole2thiolatedihydrate
AT yiguo sodium5amino134thiadiazole2thiolatedihydrate
AT luoshuping sodium5amino134thiadiazole2thiolatedihydrate

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