1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction

The title structure, C(12)H(9)N(2) (+)·C(4)H(5)O(6) (−)·3H(2)O, shows that one of the protons of d-tartaric acid has been transferred to 1,10-phenanthroline. The d-hydrogen tartrate anions are joined together in a head-to-tail fashion via a short hydrogen bond with donor–acceptor distance of 2.4554 ...

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Detalles Bibliográficos
Autores principales: Derikvand, Zohreh, Olmstead, Marilyn M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980100/
https://www.ncbi.nlm.nih.gov/pubmed/21580069
http://dx.doi.org/10.1107/S160053680905332X
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author Derikvand, Zohreh
Olmstead, Marilyn M.
author_facet Derikvand, Zohreh
Olmstead, Marilyn M.
author_sort Derikvand, Zohreh
collection PubMed
description The title structure, C(12)H(9)N(2) (+)·C(4)H(5)O(6) (−)·3H(2)O, shows that one of the protons of d-tartaric acid has been transferred to 1,10-phenanthroline. The d-hydrogen tartrate anions are joined together in a head-to-tail fashion via a short hydrogen bond with donor–acceptor distance of 2.4554 (12) Å, unsymmetrical O—H distances of 1.01 (4) Å and 1.45 (4) Å, and a 174 (4)° O—H—O bond angle. The phenanthrolinium rings are π-stacked with an average separation of 3.58 (11) Å. The structural report corrects a previous report in the literature [Wang et al. (2006 ▶). Acta Cryst. E62, o2508–o2509] of the isostructural l-hydrogen tartrate enanti­omer in which the proton transfer and short hydrogen bond were missed.
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spelling pubmed-29801002010-12-30 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction Derikvand, Zohreh Olmstead, Marilyn M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title structure, C(12)H(9)N(2) (+)·C(4)H(5)O(6) (−)·3H(2)O, shows that one of the protons of d-tartaric acid has been transferred to 1,10-phenanthroline. The d-hydrogen tartrate anions are joined together in a head-to-tail fashion via a short hydrogen bond with donor–acceptor distance of 2.4554 (12) Å, unsymmetrical O—H distances of 1.01 (4) Å and 1.45 (4) Å, and a 174 (4)° O—H—O bond angle. The phenanthrolinium rings are π-stacked with an average separation of 3.58 (11) Å. The structural report corrects a previous report in the literature [Wang et al. (2006 ▶). Acta Cryst. E62, o2508–o2509] of the isostructural l-hydrogen tartrate enanti­omer in which the proton transfer and short hydrogen bond were missed. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980100/ /pubmed/21580069 http://dx.doi.org/10.1107/S160053680905332X Text en © Derikvand and Olmstead 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Derikvand, Zohreh
Olmstead, Marilyn M.
1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title_full 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title_fullStr 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title_full_unstemmed 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title_short 1,10-Phenanthrolin-1-ium hydrogen (S,S)-tartrate trihydrate and a correction
title_sort 1,10-phenanthrolin-1-ium hydrogen (s,s)-tartrate trihydrate and a correction
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980100/
https://www.ncbi.nlm.nih.gov/pubmed/21580069
http://dx.doi.org/10.1107/S160053680905332X
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AT olmsteadmarilynm 110phenanthrolin1iumhydrogensstartratetrihydrateandacorrection

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