Ethane-1,2-diaminium 4,5-dichloro­phthalate

In the structure of the title compound, C(2)H(10)N(2) (2+)·C(8)H(2)Cl(2)O(4) (2−), the dications and dianions form hydrogen-bonded ribbon substructures which enclose conjoint cyclic R (2) (1)(7), R (1) (2)(7) and R (4) (2)(8) associations and extend down the c-axis direction. These ribbons inter-ass...

Descripción completa

Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980108/
https://www.ncbi.nlm.nih.gov/pubmed/21580117
http://dx.doi.org/10.1107/S1600536809054427
_version_ 1782191579267596288
author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the structure of the title compound, C(2)H(10)N(2) (2+)·C(8)H(2)Cl(2)O(4) (2−), the dications and dianions form hydrogen-bonded ribbon substructures which enclose conjoint cyclic R (2) (1)(7), R (1) (2)(7) and R (4) (2)(8) associations and extend down the c-axis direction. These ribbons inter-associate down b, giving a two-dimensional sheet structure. In the dianions, one of the carboxyl­ate groups is essentially coplanar with the benzene ring, while the other is normal to it [C—C—C—O torsion angles = 177.67 (12) and 81.94 (17)°, respectively].
format Text
id pubmed-2980108
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29801082010-12-30 Ethane-1,2-diaminium 4,5-dichloro­phthalate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(2)H(10)N(2) (2+)·C(8)H(2)Cl(2)O(4) (2−), the dications and dianions form hydrogen-bonded ribbon substructures which enclose conjoint cyclic R (2) (1)(7), R (1) (2)(7) and R (4) (2)(8) associations and extend down the c-axis direction. These ribbons inter-associate down b, giving a two-dimensional sheet structure. In the dianions, one of the carboxyl­ate groups is essentially coplanar with the benzene ring, while the other is normal to it [C—C—C—O torsion angles = 177.67 (12) and 81.94 (17)°, respectively]. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980108/ /pubmed/21580117 http://dx.doi.org/10.1107/S1600536809054427 Text en © Smith and Wermuth 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
Ethane-1,2-diaminium 4,5-dichloro­phthalate
title Ethane-1,2-diaminium 4,5-dichloro­phthalate
title_full Ethane-1,2-diaminium 4,5-dichloro­phthalate
title_fullStr Ethane-1,2-diaminium 4,5-dichloro­phthalate
title_full_unstemmed Ethane-1,2-diaminium 4,5-dichloro­phthalate
title_short Ethane-1,2-diaminium 4,5-dichloro­phthalate
title_sort ethane-1,2-diaminium 4,5-dichloro­phthalate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980108/
https://www.ncbi.nlm.nih.gov/pubmed/21580117
http://dx.doi.org/10.1107/S1600536809054427
work_keys_str_mv AT smithgraham ethane12diaminium45dichlorophthalate
AT wermuthursd ethane12diaminium45dichlorophthalate

Ejemplares similares