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Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2) N:N′](μ(2)-5-nitroisophthalato-κ(3) O:O′,O′′)nickel(II)]
In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octahedrally coordinated by two cis N atoms from two different 1,2-bis(4-pyridyl)ethylene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitroisophthalic acid (nip) ligand, one O atom...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980111/ https://www.ncbi.nlm.nih.gov/pubmed/21579974 http://dx.doi.org/10.1107/S1600536809053872 |
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author | Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng |
author_facet | Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng |
author_sort | Fan, Zhen-Zhong |
collection | PubMed |
description | In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octahedrally coordinated by two cis N atoms from two different 1,2-bis(4-pyridyl)ethylene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitroisophthalic acid (nip) ligand, one O atom from another monodentate nip ligand and one O atom from a water molecule, forming a three-dimensional network structure. Intermolecular O—H⋯O hydrogen bonding stabilizes this arrangement. The asymmetric unit of the structure contains one Ni(II) atom, one water molecule, one nip ligand and two half-molecules of the bpe ligand with an inversion centre at the mid-point of the central C=C bond. |
format | Text |
id | pubmed-2980111 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29801112010-12-30 Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2) N:N′](μ(2)-5-nitroisophthalato-κ(3) O:O′,O′′)nickel(II)] Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octahedrally coordinated by two cis N atoms from two different 1,2-bis(4-pyridyl)ethylene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitroisophthalic acid (nip) ligand, one O atom from another monodentate nip ligand and one O atom from a water molecule, forming a three-dimensional network structure. Intermolecular O—H⋯O hydrogen bonding stabilizes this arrangement. The asymmetric unit of the structure contains one Ni(II) atom, one water molecule, one nip ligand and two half-molecules of the bpe ligand with an inversion centre at the mid-point of the central C=C bond. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980111/ /pubmed/21579974 http://dx.doi.org/10.1107/S1600536809053872 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2) N:N′](μ(2)-5-nitroisophthalato-κ(3) O:O′,O′′)nickel(II)] |
title | Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
N:N′](μ(2)-5-nitroisophthalato-κ(3)
O:O′,O′′)nickel(II)] |
title_full | Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
N:N′](μ(2)-5-nitroisophthalato-κ(3)
O:O′,O′′)nickel(II)] |
title_fullStr | Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
N:N′](μ(2)-5-nitroisophthalato-κ(3)
O:O′,O′′)nickel(II)] |
title_full_unstemmed | Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
N:N′](μ(2)-5-nitroisophthalato-κ(3)
O:O′,O′′)nickel(II)] |
title_short | Poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
N:N′](μ(2)-5-nitroisophthalato-κ(3)
O:O′,O′′)nickel(II)] |
title_sort | poly[aqua[μ(2)-cis-1,2-bis(4-pyridyl)ethylene-κ(2)
n:n′](μ(2)-5-nitroisophthalato-κ(3)
o:o′,o′′)nickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980111/ https://www.ncbi.nlm.nih.gov/pubmed/21579974 http://dx.doi.org/10.1107/S1600536809053872 |
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