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Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]

In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octa­hedrally coordinated by two cis N atoms from two different 1,2-bis­(4-pyrid­yl)ethyl­ene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitro­isophthalic acid (nip) ligand, one O atom...

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Detalles Bibliográficos
Autores principales: Fan, Zhen-Zhong, Wang, Guo-Ping, Li, Yu-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980111/
https://www.ncbi.nlm.nih.gov/pubmed/21579974
http://dx.doi.org/10.1107/S1600536809053872
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author Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
author_facet Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
author_sort Fan, Zhen-Zhong
collection PubMed
description In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octa­hedrally coordinated by two cis N atoms from two different 1,2-bis­(4-pyrid­yl)ethyl­ene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitro­isophthalic acid (nip) ligand, one O atom from another monodentate nip ligand and one O atom from a water mol­ecule, forming a three-dimensional network structure. Inter­molecular O—H⋯O hydrogen bonding stabilizes this arrangement. The asymmetric unit of the structure contains one Ni(II) atom, one water mol­ecule, one nip ligand and two half-mol­ecules of the bpe ligand with an inversion centre at the mid-point of the central C=C bond.
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spelling pubmed-29801112010-12-30 Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)] Fan, Zhen-Zhong Wang, Guo-Ping Li, Yu-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(3)NO(6))(C(12)H(10)N(2))(H(2)O)](n), the Ni(II) atom is octa­hedrally coordinated by two cis N atoms from two different 1,2-bis­(4-pyrid­yl)ethyl­ene (bpe) ligands, two O atoms from one chelating carboxyl group of the 5-nitro­isophthalic acid (nip) ligand, one O atom from another monodentate nip ligand and one O atom from a water mol­ecule, forming a three-dimensional network structure. Inter­molecular O—H⋯O hydrogen bonding stabilizes this arrangement. The asymmetric unit of the structure contains one Ni(II) atom, one water mol­ecule, one nip ligand and two half-mol­ecules of the bpe ligand with an inversion centre at the mid-point of the central C=C bond. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980111/ /pubmed/21579974 http://dx.doi.org/10.1107/S1600536809053872 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Zhen-Zhong
Wang, Guo-Ping
Li, Yu-Sheng
Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title_full Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title_fullStr Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title_full_unstemmed Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title_short Poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) N:N′](μ(2)-5-nitro­isophthalato-κ(3) O:O′,O′′)nickel(II)]
title_sort poly[aqua­[μ(2)-cis-1,2-bis­(4-pyrid­yl)ethyl­ene-κ(2) n:n′](μ(2)-5-nitro­isophthalato-κ(3) o:o′,o′′)nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980111/
https://www.ncbi.nlm.nih.gov/pubmed/21579974
http://dx.doi.org/10.1107/S1600536809053872
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