2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide

The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol­ecules in the asymmetric unit. In each of the four mol­ecules, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to both S=O bonds. The mol­ecules are twisted at the S—N bonds with C—S...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980117/
https://www.ncbi.nlm.nih.gov/pubmed/21580075
http://dx.doi.org/10.1107/S1600536809053707
Descripción
Sumario:The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol­ecules in the asymmetric unit. In each of the four mol­ecules, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to both S=O bonds. The mol­ecules are twisted at the S—N bonds with C—SO(2)—NH—C torsion angles of 60.6 (4), −59.7 (3), 63.9 (4) and 53.0 (4)°. The benzene rings in two of the mol­ecules are disordered with multiple positions resolved in each case. The crystal structure features inversion dimers linked by pairs of N—H⋯O hydrogen bonds for each of the four molecules.

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