2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide

The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol­ecules in the asymmetric unit. In each of the four mol­ecules, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to both S=O bonds. The mol­ecules are twisted at the S—N bonds with C—S...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980117/
https://www.ncbi.nlm.nih.gov/pubmed/21580075
http://dx.doi.org/10.1107/S1600536809053707
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol­ecules in the asymmetric unit. In each of the four mol­ecules, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to both S=O bonds. The mol­ecules are twisted at the S—N bonds with C—SO(2)—NH—C torsion angles of 60.6 (4), −59.7 (3), 63.9 (4) and 53.0 (4)°. The benzene rings in two of the mol­ecules are disordered with multiple positions resolved in each case. The crystal structure features inversion dimers linked by pairs of N—H⋯O hydrogen bonds for each of the four molecules.
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spelling pubmed-29801172010-12-30 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol­ecules in the asymmetric unit. In each of the four mol­ecules, the conformation of the N—C bond in the C—SO(2)—NH—C segment is gauche with respect to both S=O bonds. The mol­ecules are twisted at the S—N bonds with C—SO(2)—NH—C torsion angles of 60.6 (4), −59.7 (3), 63.9 (4) and 53.0 (4)°. The benzene rings in two of the mol­ecules are disordered with multiple positions resolved in each case. The crystal structure features inversion dimers linked by pairs of N—H⋯O hydrogen bonds for each of the four molecules. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980117/ /pubmed/21580075 http://dx.doi.org/10.1107/S1600536809053707 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title_full 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title_fullStr 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title_full_unstemmed 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title_short 2,4-Dichloro-N-(4-methyl­phen­yl)benzene­sulfonamide
title_sort 2,4-dichloro-n-(4-methyl­phen­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980117/
https://www.ncbi.nlm.nih.gov/pubmed/21580075
http://dx.doi.org/10.1107/S1600536809053707
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AT forosabine 24dichloron4methylphenylbenzenesulfonamide
AT nirmalapg 24dichloron4methylphenylbenzenesulfonamide
AT fuesshartmut 24dichloron4methylphenylbenzenesulfonamide

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