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1,8-Bis(tosyloxy)-9,10-anthraquinone
In the crystal structure of the title compound, C(28)H(20)O(8)S(2), adjacent anthracene skeletons are parallel or inclined at an angle of 20.6 (1)°. In the molecular structure, the mean plane of the anthracene skeleton makes dihedral angles of 49.6 (1) and 76.8 (1)° with the tosyl rings, and the tw...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980119/ https://www.ncbi.nlm.nih.gov/pubmed/21580139 http://dx.doi.org/10.1107/S1600536809051009 |
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author | Niedziałkowski, Paweł Trzybiński, Damian Sikorski, Artur Ossowski, Tadeusz |
author_facet | Niedziałkowski, Paweł Trzybiński, Damian Sikorski, Artur Ossowski, Tadeusz |
author_sort | Niedziałkowski, Paweł |
collection | PubMed |
description | In the crystal structure of the title compound, C(28)H(20)O(8)S(2), adjacent anthracene skeletons are parallel or inclined at an angle of 20.6 (1)°. In the molecular structure, the mean plane of the anthracene skeleton makes dihedral angles of 49.6 (1) and 76.8 (1)° with the tosyl rings, and the two terminal benzene rings are oriented at an angle of 74.5 (1)° with respect to each other. The crystal structure is stabilized by intermolecular C—H⋯O and C—O⋯π interactions. |
format | Text |
id | pubmed-2980119 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29801192010-12-30 1,8-Bis(tosyloxy)-9,10-anthraquinone Niedziałkowski, Paweł Trzybiński, Damian Sikorski, Artur Ossowski, Tadeusz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(28)H(20)O(8)S(2), adjacent anthracene skeletons are parallel or inclined at an angle of 20.6 (1)°. In the molecular structure, the mean plane of the anthracene skeleton makes dihedral angles of 49.6 (1) and 76.8 (1)° with the tosyl rings, and the two terminal benzene rings are oriented at an angle of 74.5 (1)° with respect to each other. The crystal structure is stabilized by intermolecular C—H⋯O and C—O⋯π interactions. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980119/ /pubmed/21580139 http://dx.doi.org/10.1107/S1600536809051009 Text en © Niedziałkowski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Niedziałkowski, Paweł Trzybiński, Damian Sikorski, Artur Ossowski, Tadeusz 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title | 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title_full | 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title_fullStr | 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title_full_unstemmed | 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title_short | 1,8-Bis(tosyloxy)-9,10-anthraquinone |
title_sort | 1,8-bis(tosyloxy)-9,10-anthraquinone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980119/ https://www.ncbi.nlm.nih.gov/pubmed/21580139 http://dx.doi.org/10.1107/S1600536809051009 |
work_keys_str_mv | AT niedziałkowskipaweł 18bistosyloxy910anthraquinone AT trzybinskidamian 18bistosyloxy910anthraquinone AT sikorskiartur 18bistosyloxy910anthraquinone AT ossowskitadeusz 18bistosyloxy910anthraquinone |