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Bis(3,4-dimethoxybenzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-molecule, the complete molecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octahedral geometry with two N atoms from the phenanthroline ligand [...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980123/ https://www.ncbi.nlm.nih.gov/pubmed/21579933 http://dx.doi.org/10.1107/S1600536809052234 |
Sumario: | The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-molecule, the complete molecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octahedral geometry with two N atoms from the phenanthroline ligand [Cu—N 2.007 (2) Å] and four O atoms from two 3,4-dimethoxybenzoate ligands [Cu—O 1.950 (1) and 2.524 (1) Å]. The difference in Cu—O bond distances indicates a strong Jahn–Teller effect. In the crystal, C—H⋯π interactions result in chains of molecules along the c axis. |
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