Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)

The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-mol­ecule, the complete mol­ecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octa­hedral geometry with two N atoms from the phenanthroline ligand [...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Yaru, Sun, Junshan, Niu, Xiaoli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980123/
https://www.ncbi.nlm.nih.gov/pubmed/21579933
http://dx.doi.org/10.1107/S1600536809052234
_version_ 1782191582972215296
author Liu, Yaru
Sun, Junshan
Niu, Xiaoli
author_facet Liu, Yaru
Sun, Junshan
Niu, Xiaoli
author_sort Liu, Yaru
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-mol­ecule, the complete mol­ecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octa­hedral geometry with two N atoms from the phenanthroline ligand [Cu—N 2.007 (2) Å] and four O atoms from two 3,4-dimethoxy­benzoate ligands [Cu—O 1.950 (1) and 2.524 (1) Å]. The difference in Cu—O bond distances indicates a strong Jahn–Teller effect. In the crystal, C—H⋯π inter­actions result in chains of mol­ecules along the c axis.
format Text
id pubmed-2980123
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29801232010-12-30 Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) Liu, Yaru Sun, Junshan Niu, Xiaoli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(9)H(9)O(4))(2)(C(12)H(8)N(2))], contains one half-mol­ecule, the complete mol­ecule being generated by a twofold rotation axis. The Cu(II) atom exhibits a six-coordinated distorted octa­hedral geometry with two N atoms from the phenanthroline ligand [Cu—N 2.007 (2) Å] and four O atoms from two 3,4-dimethoxy­benzoate ligands [Cu—O 1.950 (1) and 2.524 (1) Å]. The difference in Cu—O bond distances indicates a strong Jahn–Teller effect. In the crystal, C—H⋯π inter­actions result in chains of mol­ecules along the c axis. International Union of Crystallography 2009-12-09 /pmc/articles/PMC2980123/ /pubmed/21579933 http://dx.doi.org/10.1107/S1600536809052234 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yaru
Sun, Junshan
Niu, Xiaoli
Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Bis(3,4-dimethoxy­benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort bis(3,4-dimethoxy­benzoato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980123/
https://www.ncbi.nlm.nih.gov/pubmed/21579933
http://dx.doi.org/10.1107/S1600536809052234
work_keys_str_mv AT liuyaru bis34dimethoxybenzoatok2oo110phenanthrolinek2nncopperii
AT sunjunshan bis34dimethoxybenzoatok2oo110phenanthrolinek2nncopperii
AT niuxiaoli bis34dimethoxybenzoatok2oo110phenanthrolinek2nncopperii

Ejemplares similares