catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]

In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms int...

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Detalles Bibliográficos
Autores principales: Meng, Qinglong, Wu, Yiming, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980127/
https://www.ncbi.nlm.nih.gov/pubmed/21579986
http://dx.doi.org/10.1107/S1600536809054191
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author Meng, Qinglong
Wu, Yiming
Zhang, Chi
author_facet Meng, Qinglong
Wu, Yiming
Zhang, Chi
author_sort Meng, Qinglong
collection PubMed
description In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter­act weakly with the Cu atom [Cu—Cl = 2.7870 (7) Å]. The trans 2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N—H⋯Cl and two non-classical C—H⋯Cl hydrogen bonds.
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spelling pubmed-29801272010-12-30 catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole] Meng, Qinglong Wu, Yiming Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter­act weakly with the Cu atom [Cu—Cl = 2.7870 (7) Å]. The trans 2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N—H⋯Cl and two non-classical C—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980127/ /pubmed/21579986 http://dx.doi.org/10.1107/S1600536809054191 Text en © Meng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Qinglong
Wu, Yiming
Zhang, Chi
catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title_full catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title_fullStr catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title_full_unstemmed catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title_short catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
title_sort catena-poly[[dianilinedichloridocopper(ii)]-μ(2)-2,5-bis­(4-pyrid­yl)-1,3,4-oxadiazole]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980127/
https://www.ncbi.nlm.nih.gov/pubmed/21579986
http://dx.doi.org/10.1107/S1600536809054191
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AT wuyiming catenapolydianilinedichloridocopperiim225bis4pyridyl134oxadiazole
AT zhangchi catenapolydianilinedichloridocopperiim225bis4pyridyl134oxadiazole

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