1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene

The molecule of the title compound, C(26)H(34)Br(2)N(2), lies on a crystallographic inversion center and hence the two imine groups are s-trans. The dihedral angle between the central 1,4-diaza­buta-1,3-diene unit and the attached substituted phenyl ring is 88.4 (7)°. The structure features a C—H⋯N...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Hill, Nicholas J., Van Hout, Matthew R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980129/
https://www.ncbi.nlm.nih.gov/pubmed/21580146
http://dx.doi.org/10.1107/S1600536809050843
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author Guzei, Ilia A.
Hill, Nicholas J.
Van Hout, Matthew R.
author_facet Guzei, Ilia A.
Hill, Nicholas J.
Van Hout, Matthew R.
author_sort Guzei, Ilia A.
collection PubMed
description The molecule of the title compound, C(26)H(34)Br(2)N(2), lies on a crystallographic inversion center and hence the two imine groups are s-trans. The dihedral angle between the central 1,4-diaza­buta-1,3-diene unit and the attached substituted phenyl ring is 88.4 (7)°. The structure features a C—H⋯N close contact. The crystal selected for this study proved to be a non-merohedral twin with a minor component of 21.8 (3)%.
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spelling pubmed-29801292010-12-30 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene Guzei, Ilia A. Hill, Nicholas J. Van Hout, Matthew R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(26)H(34)Br(2)N(2), lies on a crystallographic inversion center and hence the two imine groups are s-trans. The dihedral angle between the central 1,4-diaza­buta-1,3-diene unit and the attached substituted phenyl ring is 88.4 (7)°. The structure features a C—H⋯N close contact. The crystal selected for this study proved to be a non-merohedral twin with a minor component of 21.8 (3)%. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980129/ /pubmed/21580146 http://dx.doi.org/10.1107/S1600536809050843 Text en © Guzei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guzei, Ilia A.
Hill, Nicholas J.
Van Hout, Matthew R.
1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title_full 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title_fullStr 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title_full_unstemmed 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title_short 1,4-Bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
title_sort 1,4-bis(4-bromo-2,6-diisopropyl­phen­yl)-1,4-diaza­buta-1,3-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980129/
https://www.ncbi.nlm.nih.gov/pubmed/21580146
http://dx.doi.org/10.1107/S1600536809050843
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AT hillnicholasj 14bis4bromo26diisopropylphenyl14diazabuta13diene
AT vanhoutmatthewr 14bis4bromo26diisopropylphenyl14diazabuta13diene

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