Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate

In the title complex, [Cu(C(5)H(5)N(2)O(2))(C(14)H(18)N(3)O)(H(2)O)]·1.33H(2)O, the Cu(II) ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ide ligand...

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Detalles Bibliográficos
Autores principales: Zhuang, Ji-Chang, Hu, Fei-Long, Huang, Zhong-Jing, Zhuang, Yue, Zhang, Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980135/
https://www.ncbi.nlm.nih.gov/pubmed/21579972
http://dx.doi.org/10.1107/S1600536809053768
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author Zhuang, Ji-Chang
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Yue
Zhang, Feng
author_facet Zhuang, Ji-Chang
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Yue
Zhang, Feng
author_sort Zhuang, Ji-Chang
collection PubMed
description In the title complex, [Cu(C(5)H(5)N(2)O(2))(C(14)H(18)N(3)O)(H(2)O)]·1.33H(2)O, the Cu(II) ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand. The apical position is occupied by a water mol­ecule. In the crystal structure, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds lead to a three-dimensional supra­molecular network.
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spelling pubmed-29801352010-12-30 Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate Zhuang, Ji-Chang Hu, Fei-Long Huang, Zhong-Jing Zhuang, Yue Zhang, Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(5)H(5)N(2)O(2))(C(14)H(18)N(3)O)(H(2)O)]·1.33H(2)O, the Cu(II) ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand. The apical position is occupied by a water mol­ecule. In the crystal structure, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds lead to a three-dimensional supra­molecular network. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980135/ /pubmed/21579972 http://dx.doi.org/10.1107/S1600536809053768 Text en © Zhuang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhuang, Ji-Chang
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Yue
Zhang, Feng
Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title_full Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title_fullStr Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title_full_unstemmed Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title_short Aqua­[2-(5-ethyl-2-pyridyl-κN)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κN (1)](5-methyl-1H-pyrazole-3-carboxyl­ato-κ(2) N (2),O)copper(II) 1.33-hydrate
title_sort aqua­[2-(5-ethyl-2-pyridyl-κn)-4-iso­propyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ido-κn (1)](5-methyl-1h-pyrazole-3-carboxyl­ato-κ(2) n (2),o)copper(ii) 1.33-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980135/
https://www.ncbi.nlm.nih.gov/pubmed/21579972
http://dx.doi.org/10.1107/S1600536809053768
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