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Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]cobalt(II) diperchlorate
In the mononuclear title complex, [Co(C(11)H(17)N(4)O(2))(2)(CH(3)OH)(2)](ClO(4))(2), the cobalt(II) atom lies on a symmetry centre and is coordinated by two O,N-bidentate ligands and two trans-arranged O atoms of the methanol molecules in a slightly distorted octahedral geometry. In the crystal s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980142/ https://www.ncbi.nlm.nih.gov/pubmed/21579919 http://dx.doi.org/10.1107/S1600536809051782 |
| _version_ | 1782191587573366784 |
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| author | Gao, Zhi Yong Guo, Hua Jie Zhang, Wen Bei |
| author_facet | Gao, Zhi Yong Guo, Hua Jie Zhang, Wen Bei |
| author_sort | Gao, Zhi Yong |
| collection | PubMed |
| description | In the mononuclear title complex, [Co(C(11)H(17)N(4)O(2))(2)(CH(3)OH)(2)](ClO(4))(2), the cobalt(II) atom lies on a symmetry centre and is coordinated by two O,N-bidentate ligands and two trans-arranged O atoms of the methanol molecules in a slightly distorted octahedral geometry. In the crystal structure, cations and anions are linked by N—H⋯O and O—H⋯O hydrogen bonds into layers parallel to the bc plane. |
| format | Text |
| id | pubmed-2980142 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29801422010-12-30 Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]cobalt(II) diperchlorate Gao, Zhi Yong Guo, Hua Jie Zhang, Wen Bei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Co(C(11)H(17)N(4)O(2))(2)(CH(3)OH)(2)](ClO(4))(2), the cobalt(II) atom lies on a symmetry centre and is coordinated by two O,N-bidentate ligands and two trans-arranged O atoms of the methanol molecules in a slightly distorted octahedral geometry. In the crystal structure, cations and anions are linked by N—H⋯O and O—H⋯O hydrogen bonds into layers parallel to the bc plane. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980142/ /pubmed/21579919 http://dx.doi.org/10.1107/S1600536809051782 Text en © Gao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Zhi Yong Guo, Hua Jie Zhang, Wen Bei Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2) O,N]cobalt(II) diperchlorate |
| title | Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
O,N]cobalt(II) diperchlorate |
| title_full | Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
O,N]cobalt(II) diperchlorate |
| title_fullStr | Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
O,N]cobalt(II) diperchlorate |
| title_full_unstemmed | Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
O,N]cobalt(II) diperchlorate |
| title_short | Dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
O,N]cobalt(II) diperchlorate |
| title_sort | dimethanolbis[4,4,5,5-tetramethyl-2-(5-methylimidazol-4-yl)-2-imidazoline-1-oxyl-3-oxide-κ(2)
o,n]cobalt(ii) diperchlorate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980142/ https://www.ncbi.nlm.nih.gov/pubmed/21579919 http://dx.doi.org/10.1107/S1600536809051782 |
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