Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate

In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in...

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Detalles Bibliográficos
Autores principales: Zhang, Feng, Hu, Fei-Long, Huang, Zhong-Jing, Zhuang, Ji-Chang, Zhuang, Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980145/
https://www.ncbi.nlm.nih.gov/pubmed/21579969
http://dx.doi.org/10.1107/S160053680905377X
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author Zhang, Feng
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Ji-Chang
Zhuang, Yue
author_facet Zhang, Feng
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Ji-Chang
Zhuang, Yue
author_sort Zhang, Feng
collection PubMed
description In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent mol­ecule is linked to a triazole group via an O—H⋯N hydrogen bond.
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spelling pubmed-29801452010-12-30 Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate Zhang, Feng Hu, Fei-Long Huang, Zhong-Jing Zhuang, Ji-Chang Zhuang, Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent mol­ecule is linked to a triazole group via an O—H⋯N hydrogen bond. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980145/ /pubmed/21579969 http://dx.doi.org/10.1107/S160053680905377X Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Feng
Hu, Fei-Long
Huang, Zhong-Jing
Zhuang, Ji-Chang
Zhuang, Yue
Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title_full Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title_fullStr Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title_full_unstemmed Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title_short Bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) N (2),O:O,N (2′)]bis­[(acetato-κ(2) O,O′)nickel(II)] methanol hemisolvate
title_sort bis[μ-2-(2,4-difluoro­phen­yl)-1,3-bis­(1,2,4-triazol-1-yl)propan-2-olato-κ(4) n (2),o:o,n (2′)]bis­[(acetato-κ(2) o,o′)nickel(ii)] methanol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980145/
https://www.ncbi.nlm.nih.gov/pubmed/21579969
http://dx.doi.org/10.1107/S160053680905377X
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