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(E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate
The 30 non-H atoms in title dihydrazine compound, C(20)H(16)N(6)O(4)·2H(2)O, are close to coplanar, the r.m.s. deviation for these atoms being 0.096 Å. The conformation about each of the C=N bonds is E, and the molecule has non-crystallographic 2/m symmetry. The presence of O—H⋯O and N—H⋯O hydrogen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980149/ https://www.ncbi.nlm.nih.gov/pubmed/21580076 http://dx.doi.org/10.1107/S1600536809053963 |
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author | Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
author_facet | Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
author_sort | Tiekink, Edward R. T. |
collection | PubMed |
description | The 30 non-H atoms in title dihydrazine compound, C(20)H(16)N(6)O(4)·2H(2)O, are close to coplanar, the r.m.s. deviation for these atoms being 0.096 Å. The conformation about each of the C=N bonds is E, and the molecule has non-crystallographic 2/m symmetry. The presence of O—H⋯O and N—H⋯O hydrogen bonding leads to a three-dimensional network in the crystal structure. A highly disordered solvent molecule is present within a molecular cavity defined by the organic and water molecules. Its contribution to the electron density was removed from the observed data in the final cycles of refinement and the formula, molecular weight and density are given without taking into account the contribution of the solvent molecule. |
format | Text |
id | pubmed-2980149 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29801492010-12-30 (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 30 non-H atoms in title dihydrazine compound, C(20)H(16)N(6)O(4)·2H(2)O, are close to coplanar, the r.m.s. deviation for these atoms being 0.096 Å. The conformation about each of the C=N bonds is E, and the molecule has non-crystallographic 2/m symmetry. The presence of O—H⋯O and N—H⋯O hydrogen bonding leads to a three-dimensional network in the crystal structure. A highly disordered solvent molecule is present within a molecular cavity defined by the organic and water molecules. Its contribution to the electron density was removed from the observed data in the final cycles of refinement and the formula, molecular weight and density are given without taking into account the contribution of the solvent molecule. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980149/ /pubmed/21580076 http://dx.doi.org/10.1107/S1600536809053963 Text en © Tiekink et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title | (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title_full | (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title_fullStr | (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title_full_unstemmed | (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title_short | (E)-1-(4-Nitrophenyl)-2-(4-{[(E)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
title_sort | (e)-1-(4-nitrophenyl)-2-(4-{[(e)-2-(4-nitrophenyl)hydrazinylidene]methyl}benzylidene)hydrazine dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980149/ https://www.ncbi.nlm.nih.gov/pubmed/21580076 http://dx.doi.org/10.1107/S1600536809053963 |
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