Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate

In the title molecular salt, C(16)H(36)N(+)·C(12)H(20)BS(3) (−), three of the four n-butyl chains show a trans conformation, whereas the fourth has the C—C—C—C torsion angle in a gauche conformation [−77.8 (5)°]. In the crystal, mol­ecules are packed in layers parallel to the (101) plane....

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Detalles Bibliográficos
Autores principales: Tillmann, Jan, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980150/
https://www.ncbi.nlm.nih.gov/pubmed/21580088
http://dx.doi.org/10.1107/S1600536809054026
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author Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Tillmann, Jan
collection PubMed
description In the title molecular salt, C(16)H(36)N(+)·C(12)H(20)BS(3) (−), three of the four n-butyl chains show a trans conformation, whereas the fourth has the C—C—C—C torsion angle in a gauche conformation [−77.8 (5)°]. In the crystal, mol­ecules are packed in layers parallel to the (101) plane.
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spelling pubmed-29801502010-12-30 Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate Tillmann, Jan Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(16)H(36)N(+)·C(12)H(20)BS(3) (−), three of the four n-butyl chains show a trans conformation, whereas the fourth has the C—C—C—C torsion angle in a gauche conformation [−77.8 (5)°]. In the crystal, mol­ecules are packed in layers parallel to the (101) plane. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980150/ /pubmed/21580088 http://dx.doi.org/10.1107/S1600536809054026 Text en © Tillmann et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title_full Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title_fullStr Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title_full_unstemmed Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title_short Tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
title_sort tetra­butyl­ammonium tris­(methyl­sulfanylmeth­yl)phenyl­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980150/
https://www.ncbi.nlm.nih.gov/pubmed/21580088
http://dx.doi.org/10.1107/S1600536809054026
work_keys_str_mv AT tillmannjan tetrabutylammoniumtrismethylsulfanylmethylphenylborate
AT lernerhanswolfram tetrabutylammoniumtrismethylsulfanylmethylphenylborate
AT boltemichael tetrabutylammoniumtrismethylsulfanylmethylphenylborate

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