Cargando…
Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980155/ https://www.ncbi.nlm.nih.gov/pubmed/21579936 http://dx.doi.org/10.1107/S1600536809052313 |
Sumario: | In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar molecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π–π interactions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H⋯Cl interaction is observed between the columns. |
---|