Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)

In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol­ecules, with a maximum deviation of 0.120 (3) Å from the least-...

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Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980155/
https://www.ncbi.nlm.nih.gov/pubmed/21579936
http://dx.doi.org/10.1107/S1600536809052313
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol­ecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π–π inter­actions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H⋯Cl inter­action is observed between the columns.
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spelling pubmed-29801552010-12-30 Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol­ecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π–π inter­actions between adjacent six-membered rings are present, the shortest centroid–centroid distance being 3.680 (4) Å. A weak C—H⋯Cl inter­action is observed between the columns. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980155/ /pubmed/21579936 http://dx.doi.org/10.1107/S1600536809052313 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title_full Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title_fullStr Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title_full_unstemmed Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title_short Dichlorido(1,10-phenanthroline-κ(2) N,N′)palladium(II)
title_sort dichlorido(1,10-phenanthroline-κ(2) n,n′)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980155/
https://www.ncbi.nlm.nih.gov/pubmed/21579936
http://dx.doi.org/10.1107/S1600536809052313
work_keys_str_mv AT hakwang dichlorido110phenanthrolinek2nnpalladiumii

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