Bis(2-naphthyl­meth­yl)diphenyl­silane

The title compound, C(34)H(28)Si, was prepared as an inter­nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra­hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system...

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Detalles Bibliográficos
Autores principales: Monroe, Thomas Blake, Thomas, Andy A., Jones, Daniel S., Ogle, Craig A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980158/
https://www.ncbi.nlm.nih.gov/pubmed/21580023
http://dx.doi.org/10.1107/S1600536809047412
Descripción
Sumario:The title compound, C(34)H(28)Si, was prepared as an inter­nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra­hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18 (6)° with one another. In the crystal, the mol­ecules pack in columns parallel to the a axis, and exhibit arene C—H⋯π(arene) inter­actions both within and between columns.

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