Bis(2-naphthyl­meth­yl)diphenyl­silane

The title compound, C(34)H(28)Si, was prepared as an inter­nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra­hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system...

Descripción completa

Detalles Bibliográficos
Autores principales: Monroe, Thomas Blake, Thomas, Andy A., Jones, Daniel S., Ogle, Craig A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980158/
https://www.ncbi.nlm.nih.gov/pubmed/21580023
http://dx.doi.org/10.1107/S1600536809047412
_version_ 1782191591438417920
author Monroe, Thomas Blake
Thomas, Andy A.
Jones, Daniel S.
Ogle, Craig A.
author_facet Monroe, Thomas Blake
Thomas, Andy A.
Jones, Daniel S.
Ogle, Craig A.
author_sort Monroe, Thomas Blake
collection PubMed
description The title compound, C(34)H(28)Si, was prepared as an inter­nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra­hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18 (6)° with one another. In the crystal, the mol­ecules pack in columns parallel to the a axis, and exhibit arene C—H⋯π(arene) inter­actions both within and between columns.
format Text
id pubmed-2980158
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29801582010-12-30 Bis(2-naphthyl­meth­yl)diphenyl­silane Monroe, Thomas Blake Thomas, Andy A. Jones, Daniel S. Ogle, Craig A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(34)H(28)Si, was prepared as an inter­nal standard for diffusion-ordered NMR spectroscopy. The four ligands are arranged tetra­hedrally around the Si atom. The two naphthalene systems are nearly perpendicular, making an angle of 86.42 (4)° with one another. A naphthalene system and a phenyl ring are also nearly perpendicular, making an angle of 86.18 (6)° with one another. In the crystal, the mol­ecules pack in columns parallel to the a axis, and exhibit arene C—H⋯π(arene) inter­actions both within and between columns. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980158/ /pubmed/21580023 http://dx.doi.org/10.1107/S1600536809047412 Text en © Monroe et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Monroe, Thomas Blake
Thomas, Andy A.
Jones, Daniel S.
Ogle, Craig A.
Bis(2-naphthyl­meth­yl)diphenyl­silane
title Bis(2-naphthyl­meth­yl)diphenyl­silane
title_full Bis(2-naphthyl­meth­yl)diphenyl­silane
title_fullStr Bis(2-naphthyl­meth­yl)diphenyl­silane
title_full_unstemmed Bis(2-naphthyl­meth­yl)diphenyl­silane
title_short Bis(2-naphthyl­meth­yl)diphenyl­silane
title_sort bis(2-naphthyl­meth­yl)diphenyl­silane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980158/
https://www.ncbi.nlm.nih.gov/pubmed/21580023
http://dx.doi.org/10.1107/S1600536809047412
work_keys_str_mv AT monroethomasblake bis2naphthylmethyldiphenylsilane
AT thomasandya bis2naphthylmethyldiphenylsilane
AT jonesdaniels bis2naphthylmethyldiphenylsilane
AT oglecraiga bis2naphthylmethyldiphenylsilane

Ejemplares similares