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Chlorido[3,3′-dibutyl-5,5′-(pyridine-2,6-di­yl)dipyrazol-1-ido]gold(III)

The Au atom in the C2-symmetric pincer-type title complex, [AuCl(C(19)H(23)N(5))], is in the +3 oxidation state. The ligand is composed of one pyridine unit and two n-butyl-substituted pyrazoles (pyrz). Both pyrazoles are deprotonated, thus forming a neutral compound. To the best of our knowledge, t...

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Detalles Bibliográficos
Autores principales: Hashmi, A. Stephen K., Lothschütz, Christian, Rominger, Frank
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980159/
https://www.ncbi.nlm.nih.gov/pubmed/21579959
http://dx.doi.org/10.1107/S1600536809050995
Descripción
Sumario:The Au atom in the C2-symmetric pincer-type title complex, [AuCl(C(19)H(23)N(5))], is in the +3 oxidation state. The ligand is composed of one pyridine unit and two n-butyl-substituted pyrazoles (pyrz). Both pyrazoles are deprotonated, thus forming a neutral compound. To the best of our knowledge, this is the first Au(III)–bis­pyrazolate complex. According to the special geometry in the N,N′,N′′-tridentate ligand, containing two five-membered heterocycles, the complex deviates from an ideal square-planar coordination geometry; the N(pyrz)—Au—N(pyrz) angle is 160.8 (3)°, indicating a distortion of nearly 20°.