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Aqua(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water molecule in a distorted square-pyramidal geometry. The crystal s...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980168/ https://www.ncbi.nlm.nih.gov/pubmed/21579963 http://dx.doi.org/10.1107/S1600536809053483 |
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author | Yang, Xiao-Xia Zhang, Fu-Yong Xu, Shi-Hai |
author_facet | Yang, Xiao-Xia Zhang, Fu-Yong Xu, Shi-Hai |
author_sort | Yang, Xiao-Xia |
collection | PubMed |
description | In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water molecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via intermolecular O—H⋯O and C—H⋯O hydrogen bonds, C—H⋯π interactions and π–π stacking interactions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å]. |
format | Text |
id | pubmed-2980168 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29801682010-12-30 Aqua(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) Yang, Xiao-Xia Zhang, Fu-Yong Xu, Shi-Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water molecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via intermolecular O—H⋯O and C—H⋯O hydrogen bonds, C—H⋯π interactions and π–π stacking interactions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å]. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980168/ /pubmed/21579963 http://dx.doi.org/10.1107/S1600536809053483 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Xiao-Xia Zhang, Fu-Yong Xu, Shi-Hai Aqua(2-oxido-2,2-diphenylacetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) |
title | Aqua(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Aqua(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Aqua(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Aqua(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Aqua(2-oxido-2,2-diphenylacetato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | aqua(2-oxido-2,2-diphenylacetato-κ(2)
o
(1),o
(2))(1,10-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980168/ https://www.ncbi.nlm.nih.gov/pubmed/21579963 http://dx.doi.org/10.1107/S1600536809053483 |
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