Cargando…

Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water mol­ecule in a distorted square-pyramidal geometry. The crystal s...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Xiao-Xia, Zhang, Fu-Yong, Xu, Shi-Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980168/
https://www.ncbi.nlm.nih.gov/pubmed/21579963
http://dx.doi.org/10.1107/S1600536809053483
_version_ 1782191593870065664
author Yang, Xiao-Xia
Zhang, Fu-Yong
Xu, Shi-Hai
author_facet Yang, Xiao-Xia
Zhang, Fu-Yong
Xu, Shi-Hai
author_sort Yang, Xiao-Xia
collection PubMed
description In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water mol­ecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds, C—H⋯π inter­actions and π–π stacking inter­actions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å].
format Text
id pubmed-2980168
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29801682010-12-30 Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) Yang, Xiao-Xia Zhang, Fu-Yong Xu, Shi-Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water mol­ecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds, C—H⋯π inter­actions and π–π stacking inter­actions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å]. International Union of Crystallography 2009-12-16 /pmc/articles/PMC2980168/ /pubmed/21579963 http://dx.doi.org/10.1107/S1600536809053483 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Xiao-Xia
Zhang, Fu-Yong
Xu, Shi-Hai
Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­(2-oxido-2,2-diphenyl­acetato-κ(2) o (1),o (2))(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980168/
https://www.ncbi.nlm.nih.gov/pubmed/21579963
http://dx.doi.org/10.1107/S1600536809053483
work_keys_str_mv AT yangxiaoxia aqua2oxido22diphenylacetatok2o1o2110phenanthrolinek2nncopperii
AT zhangfuyong aqua2oxido22diphenylacetatok2o1o2110phenanthrolinek2nncopperii
AT xushihai aqua2oxido22diphenylacetatok2o1o2110phenanthrolinek2nncopperii