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Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec)
In the title dihalogenated trichodermin molecule, C(17)H(24)Br(2)O(4) (systematic name: 9,10-dibromo-12,13-epoxytrichothec-9-en-4β-yl acetate), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the same conformation, viz. chair. As for the seven-memb...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980171/ https://www.ncbi.nlm.nih.gov/pubmed/21580095 http://dx.doi.org/10.1107/S1600536809054178 |
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| author | Zhao, Jin-Hao Zhou, Yong Zhang, Jian-Gong Cheng, Jing-Li Lin, Fu-Cheng |
| author_facet | Zhao, Jin-Hao Zhou, Yong Zhang, Jian-Gong Cheng, Jing-Li Lin, Fu-Cheng |
| author_sort | Zhao, Jin-Hao |
| collection | PubMed |
| description | In the title dihalogenated trichodermin molecule, C(17)H(24)Br(2)O(4) (systematic name: 9,10-dibromo-12,13-epoxytrichothec-9-en-4β-yl acetate), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the same conformation, viz. chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.53 (4) and 88.67 (4)°, respectively. |
| format | Text |
| id | pubmed-2980171 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29801712010-12-30 Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) Zhao, Jin-Hao Zhou, Yong Zhang, Jian-Gong Cheng, Jing-Li Lin, Fu-Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title dihalogenated trichodermin molecule, C(17)H(24)Br(2)O(4) (systematic name: 9,10-dibromo-12,13-epoxytrichothec-9-en-4β-yl acetate), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the same conformation, viz. chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.53 (4) and 88.67 (4)°, respectively. International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980171/ /pubmed/21580095 http://dx.doi.org/10.1107/S1600536809054178 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Zhao, Jin-Hao Zhou, Yong Zhang, Jian-Gong Cheng, Jing-Li Lin, Fu-Cheng Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title | Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title_full | Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title_fullStr | Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title_full_unstemmed | Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title_short | Dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| title_sort | dihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980171/ https://www.ncbi.nlm.nih.gov/pubmed/21580095 http://dx.doi.org/10.1107/S1600536809054178 |
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