Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)

In the title compound, [Co(C(10)H(8)N(2))(3)][W(CN)(8)], the Co atom (..2 site symmetry) is coordinated by six N atoms from three 2,2′-bipyridine ligands in an octa­hedral geometry; the Co—N bond distances range from 1.926 (2) to 1.939 (2) Å. The W (..2 site symmetry) metal center is coordinated by...

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Detalles Bibliográficos
Autores principales: Jun, Qian, Zhang, Chi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980176/
https://www.ncbi.nlm.nih.gov/pubmed/21579913
http://dx.doi.org/10.1107/S1600536809051654
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author Jun, Qian
Zhang, Chi
author_facet Jun, Qian
Zhang, Chi
author_sort Jun, Qian
collection PubMed
description In the title compound, [Co(C(10)H(8)N(2))(3)][W(CN)(8)], the Co atom (..2 site symmetry) is coordinated by six N atoms from three 2,2′-bipyridine ligands in an octa­hedral geometry; the Co—N bond distances range from 1.926 (2) to 1.939 (2) Å. The W (..2 site symmetry) metal center is coordinated by eight cyanide ligands, resulting in a dodeca­hedral conformation with W—C distances in the range 1.165 (3)–2.176 (3) Å. The cations and anions are linked into a three-demensional structure by weak C—H⋯N hydrogen bonds.
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spelling pubmed-29801762010-12-30 Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V) Jun, Qian Zhang, Chi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(8)N(2))(3)][W(CN)(8)], the Co atom (..2 site symmetry) is coordinated by six N atoms from three 2,2′-bipyridine ligands in an octa­hedral geometry; the Co—N bond distances range from 1.926 (2) to 1.939 (2) Å. The W (..2 site symmetry) metal center is coordinated by eight cyanide ligands, resulting in a dodeca­hedral conformation with W—C distances in the range 1.165 (3)–2.176 (3) Å. The cations and anions are linked into a three-demensional structure by weak C—H⋯N hydrogen bonds. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980176/ /pubmed/21579913 http://dx.doi.org/10.1107/S1600536809051654 Text en © Jun and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jun, Qian
Zhang, Chi
Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title_full Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title_fullStr Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title_full_unstemmed Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title_short Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(III) octa­cyanido­tungstate(V)
title_sort tris(2,2′-bipyridine-κ(2) n,n′)cobalt(iii) octa­cyanido­tungstate(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980176/
https://www.ncbi.nlm.nih.gov/pubmed/21579913
http://dx.doi.org/10.1107/S1600536809051654
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AT zhangchi tris22bipyridinek2nncobaltiiioctacyanidotungstatev

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