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Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II)
In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980185/ https://www.ncbi.nlm.nih.gov/pubmed/21579910 http://dx.doi.org/10.1107/S1600536809054518 |
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author | Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng |
author_facet | Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng |
author_sort | Sadeghi, Omid |
collection | PubMed |
description | In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn(II) atoms are disordered with respect to the Fe(III) atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. |
format | Text |
id | pubmed-2980185 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29801852010-12-30 Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn(II) atoms are disordered with respect to the Fe(III) atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980185/ /pubmed/21579910 http://dx.doi.org/10.1107/S1600536809054518 Text en © Sadeghi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title | Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title_full | Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title_fullStr | Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title_full_unstemmed | Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title_short | Diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(III)manganese(II) |
title_sort | diaquahexa-μ(2)-dichloroacetato-μ(3)-oxido-tetrahydrofurandiiron(iii)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980185/ https://www.ncbi.nlm.nih.gov/pubmed/21579910 http://dx.doi.org/10.1107/S1600536809054518 |
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