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Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)

In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloro­acetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water...

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Detalles Bibliográficos
Autores principales: Sadeghi, Omid, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980185/
https://www.ncbi.nlm.nih.gov/pubmed/21579910
http://dx.doi.org/10.1107/S1600536809054518
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author Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_facet Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_sort Sadeghi, Omid
collection PubMed
description In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloro­acetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water mol­ecule, whereas the third is coordinated by a tetra­hydro­furan mol­ecule. In the crystal, adjacent mol­ecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn(II) atoms are disordered with respect to the Fe(III) atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe.
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spelling pubmed-29801852010-12-30 Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II) Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the oxido-centered title compound, [Fe(2)Mn(C(2)HCl(2)O(2))(6)O(C(4)H(8)O)(H(2)O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloro­acetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water mol­ecule, whereas the third is coordinated by a tetra­hydro­furan mol­ecule. In the crystal, adjacent mol­ecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn(II) atoms are disordered with respect to the Fe(III) atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980185/ /pubmed/21579910 http://dx.doi.org/10.1107/S1600536809054518 Text en © Sadeghi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title_full Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title_fullStr Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title_full_unstemmed Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title_short Diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(III)manganese(II)
title_sort diaqua­hexa-μ(2)-dichloro­acetato-μ(3)-oxido-tetra­hydro­furan­diiron(iii)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980185/
https://www.ncbi.nlm.nih.gov/pubmed/21579910
http://dx.doi.org/10.1107/S1600536809054518
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