Poly[hexa­aqua­bis(μ(3)-terephthalato)(μ(2)-terephthalato)diytterbium(III)]

In the title two-dimensional coordination polymer, [Yb(2)(C(8)H(4)O(4))(3)(H(2)O)(6)](n), the unique Yb(III) ion is eight-coordinated in a distorted dodeca­hedral coordination geometry by three water O atoms and five O atoms from carboxyl­ate groups belonging to four different terephthalate ligands....

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Detalles Bibliográficos
Autor principal: Feng, Sun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980195/
https://www.ncbi.nlm.nih.gov/pubmed/21579932
http://dx.doi.org/10.1107/S160053680905171X
Descripción
Sumario:In the title two-dimensional coordination polymer, [Yb(2)(C(8)H(4)O(4))(3)(H(2)O)(6)](n), the unique Yb(III) ion is eight-coordinated in a distorted dodeca­hedral coordination geometry by three water O atoms and five O atoms from carboxyl­ate groups belonging to four different terephthalate ligands. One of the terephthalate ligands is located around an inversion center. The coordination polymers are parallel to (121) and are connected by O—H⋯O hydrogen bonds into a three-dimensional framework.

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