Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate

In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Mn(II) atom, lying on an inversion centre, is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carb­oxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. In the crystal struc...

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Detalles Bibliográficos
Autores principales: Yan, Jian-Bin, Li, Shi-Jie, Song, Wen-Dong, Wang, Hao, Miao, Dong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980198/
https://www.ncbi.nlm.nih.gov/pubmed/21579988
http://dx.doi.org/10.1107/S1600536809054634
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author Yan, Jian-Bin
Li, Shi-Jie
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
author_facet Yan, Jian-Bin
Li, Shi-Jie
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
author_sort Yan, Jian-Bin
collection PubMed
description In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Mn(II) atom, lying on an inversion centre, is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carb­oxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. In the crystal structure, the complex mol­ecules and dimethyl­formamide solvent mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a two-dimensional supra­molecular network parallel to (001).
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spelling pubmed-29801982010-12-30 Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate Yan, Jian-Bin Li, Shi-Jie Song, Wen-Dong Wang, Hao Miao, Dong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Mn(II) atom, lying on an inversion centre, is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carb­oxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. In the crystal structure, the complex mol­ecules and dimethyl­formamide solvent mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds into a two-dimensional supra­molecular network parallel to (001). International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980198/ /pubmed/21579988 http://dx.doi.org/10.1107/S1600536809054634 Text en © Yan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yan, Jian-Bin
Li, Shi-Jie
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title_full Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title_fullStr Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title_short Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) N,N-dimethyl­formamide disolvate
title_sort diaqua­bis(5-carb­oxy-2-propyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))manganese(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980198/
https://www.ncbi.nlm.nih.gov/pubmed/21579988
http://dx.doi.org/10.1107/S1600536809054634
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