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Poly[tetrakis(μ-cyclohexane-1,4-dicarboxylato)di-μ-hydroxido-pentazinc(II)]
In the title coordination polymer, [Zn(5)(μ(3)-OH)(2)(1,4-CDC)(4)](n) (1,4-CDCH(2) = 1,4-cyclohexanedicarboxylic acid) or [Zn(5)(C(8)H(10)O(4))(4)(OH)(2)](n), the asymmetric unit comprises one half of an octahedrally coordinated ZnO(6) complex unit (site symmetry [Image: see text]) and two five-c...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980201/ https://www.ncbi.nlm.nih.gov/pubmed/21579917 http://dx.doi.org/10.1107/S1600536809051666 |
Sumario: | In the title coordination polymer, [Zn(5)(μ(3)-OH)(2)(1,4-CDC)(4)](n) (1,4-CDCH(2) = 1,4-cyclohexanedicarboxylic acid) or [Zn(5)(C(8)H(10)O(4))(4)(OH)(2)](n), the asymmetric unit comprises one half of an octahedrally coordinated ZnO(6) complex unit (site symmetry [Image: see text]) and two five-coordinate ZnO(5) complex units, together with two μ(3)-bridging hydroxido ligands and four 1,4-CDC ligands (comprising two whole molecules and four inversion-related half-molecules). The ZnO(6) unit consists of four carboxylate O donors (two bridging) and two hydroxido O donors (both bridging three Zn centres) [Zn—O range 2.065 (3)–2.125 (3) Å]. Each of the ZnO(5) units [one capped tetrahedral, the other square-pyrimidal; Zn—O range 1.928 (3)–2.338 (3) Å] has one hydroxido O donor and four carboxyl O donors from three different 1,4-CDC carboxylate O donors (one bridging). Infinite (ZnO)(n) inorganic chains run parallel to the a axis and are interconnected by the organic ligands into a three-dimensional structure. |
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