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3-Anilino-N-p-tolylbenzamide
The title compound, C(20)H(18)N(2)O, which crystallizes with two independent molecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent molecules is slightly different. The dihedral angles between the central aromatic ri...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980203/ https://www.ncbi.nlm.nih.gov/pubmed/21580005 http://dx.doi.org/10.1107/S1600536809049939 |
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author | Yang, Xing-Xing Liu, Guan-Feng Qin, Da-Bin |
author_facet | Yang, Xing-Xing Liu, Guan-Feng Qin, Da-Bin |
author_sort | Yang, Xing-Xing |
collection | PubMed |
description | The title compound, C(20)H(18)N(2)O, which crystallizes with two independent molecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent molecules is slightly different. The dihedral angles between the central aromatic ring II and rings I and III are 47.13 (9) and 89.36 (9)°, respectively, for molecule A, and 29.60 (9) and 70.72 (9)°, respectively, for molecule B. Rings I and III are inclined to one another by 86.57 (9)° in molecule A, and 64.59 (10)° in molecule B. The molecular structures are stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains propagating in the [010] direction. In addition, a number of C—H⋯π interactions are observed. |
format | Text |
id | pubmed-2980203 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29802032010-12-30 3-Anilino-N-p-tolylbenzamide Yang, Xing-Xing Liu, Guan-Feng Qin, Da-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(18)N(2)O, which crystallizes with two independent molecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent molecules is slightly different. The dihedral angles between the central aromatic ring II and rings I and III are 47.13 (9) and 89.36 (9)°, respectively, for molecule A, and 29.60 (9) and 70.72 (9)°, respectively, for molecule B. Rings I and III are inclined to one another by 86.57 (9)° in molecule A, and 64.59 (10)° in molecule B. The molecular structures are stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal structure, molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming chains propagating in the [010] direction. In addition, a number of C—H⋯π interactions are observed. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980203/ /pubmed/21580005 http://dx.doi.org/10.1107/S1600536809049939 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yang, Xing-Xing Liu, Guan-Feng Qin, Da-Bin 3-Anilino-N-p-tolylbenzamide |
title | 3-Anilino-N-p-tolylbenzamide |
title_full | 3-Anilino-N-p-tolylbenzamide |
title_fullStr | 3-Anilino-N-p-tolylbenzamide |
title_full_unstemmed | 3-Anilino-N-p-tolylbenzamide |
title_short | 3-Anilino-N-p-tolylbenzamide |
title_sort | 3-anilino-n-p-tolylbenzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980203/ https://www.ncbi.nlm.nih.gov/pubmed/21580005 http://dx.doi.org/10.1107/S1600536809049939 |
work_keys_str_mv | AT yangxingxing 3anilinonptolylbenzamide AT liuguanfeng 3anilinonptolylbenzamide AT qindabin 3anilinonptolylbenzamide |