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3-Anilino-N-p-tolyl­benzamide

The title compound, C(20)H(18)N(2)O, which crystallizes with two independent mol­ecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent mol­ecules is slightly different. The dihedral angles between the central aromatic ri...

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Detalles Bibliográficos
Autores principales: Yang, Xing-Xing, Liu, Guan-Feng, Qin, Da-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980203/
https://www.ncbi.nlm.nih.gov/pubmed/21580005
http://dx.doi.org/10.1107/S1600536809049939
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author Yang, Xing-Xing
Liu, Guan-Feng
Qin, Da-Bin
author_facet Yang, Xing-Xing
Liu, Guan-Feng
Qin, Da-Bin
author_sort Yang, Xing-Xing
collection PubMed
description The title compound, C(20)H(18)N(2)O, which crystallizes with two independent mol­ecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent mol­ecules is slightly different. The dihedral angles between the central aromatic ring II and rings I and III are 47.13 (9) and 89.36 (9)°, respectively, for mol­ecule A, and 29.60 (9) and 70.72 (9)°, respectively, for mol­ecule B. Rings I and III are inclined to one another by 86.57 (9)° in mol­ecule A, and 64.59 (10)° in mol­ecule B. The mol­ecular structures are stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains propagating in the [010] direction. In addition, a number of C—H⋯π inter­actions are observed.
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spelling pubmed-29802032010-12-30 3-Anilino-N-p-tolyl­benzamide Yang, Xing-Xing Liu, Guan-Feng Qin, Da-Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(18)N(2)O, which crystallizes with two independent mol­ecules (A and B) in the asymmetric unit, is composed of three aromatic rings (I, II and III). The conformation of the two independent mol­ecules is slightly different. The dihedral angles between the central aromatic ring II and rings I and III are 47.13 (9) and 89.36 (9)°, respectively, for mol­ecule A, and 29.60 (9) and 70.72 (9)°, respectively, for mol­ecule B. Rings I and III are inclined to one another by 86.57 (9)° in mol­ecule A, and 64.59 (10)° in mol­ecule B. The mol­ecular structures are stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming chains propagating in the [010] direction. In addition, a number of C—H⋯π inter­actions are observed. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980203/ /pubmed/21580005 http://dx.doi.org/10.1107/S1600536809049939 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Xing-Xing
Liu, Guan-Feng
Qin, Da-Bin
3-Anilino-N-p-tolyl­benzamide
title 3-Anilino-N-p-tolyl­benzamide
title_full 3-Anilino-N-p-tolyl­benzamide
title_fullStr 3-Anilino-N-p-tolyl­benzamide
title_full_unstemmed 3-Anilino-N-p-tolyl­benzamide
title_short 3-Anilino-N-p-tolyl­benzamide
title_sort 3-anilino-n-p-tolyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980203/
https://www.ncbi.nlm.nih.gov/pubmed/21580005
http://dx.doi.org/10.1107/S1600536809049939
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AT liuguanfeng 3anilinonptolylbenzamide
AT qindabin 3anilinonptolylbenzamide