catena-Poly[[trimethyltin(IV)]-μ-2-methylbenzoato-κ(2) O:O′]

The polymeric structure of the title compound, [Sn(CH(3))(3)(C(8)H(7)O(2))](n), is composed of zigzag chains in which the tin(IV) atoms, coordinated by three methyl groups, are bridged by toluene-2-carboxyl­ate ligands via their O atoms. A slightly distorted trigonal-bipyramidal SnC(3)O(2) coordinat...

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Detalles Bibliográficos
Autores principales: Danish, Muhammad, Saleem, Iram, Ahmad, Nazir, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980210/
https://www.ncbi.nlm.nih.gov/pubmed/21579938
http://dx.doi.org/10.1107/S1600536809051587
Descripción
Sumario:The polymeric structure of the title compound, [Sn(CH(3))(3)(C(8)H(7)O(2))](n), is composed of zigzag chains in which the tin(IV) atoms, coordinated by three methyl groups, are bridged by toluene-2-carboxyl­ate ligands via their O atoms. A slightly distorted trigonal-bipyramidal SnC(3)O(2) coordination geometry arises for the metal, with the O atoms in the axial sites. Weak C—H⋯O hydrogen bonds help to stabilize the packing.

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