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μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}

The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl­ate group of the adipate unit by an...

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Detalles Bibliográficos
Autores principales: Wei, Lian-Qiang, Zeng, Ming-Hua, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980214/
https://www.ncbi.nlm.nih.gov/pubmed/21579952
http://dx.doi.org/10.1107/S1600536809052647
Descripción
Sumario:The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl­ate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Ψ-octa­hedral coordination environment. When weaker Pb⋯O inter­actions are also considered, the geometry is a Ψ-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent mol­ecules are linked into a layer structure by N—H⋯O hydrogen bonds.