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μ-Adipato-κ(2) O (1):O (4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by an...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980214/ https://www.ncbi.nlm.nih.gov/pubmed/21579952 http://dx.doi.org/10.1107/S1600536809052647 |
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author | Wei, Lian-Qiang Zeng, Ming-Hua Ng, Seik Weng |
author_facet | Wei, Lian-Qiang Zeng, Ming-Hua Ng, Seik Weng |
author_sort | Wei, Lian-Qiang |
collection | PubMed |
description | The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Ψ-octahedral coordination environment. When weaker Pb⋯O interactions are also considered, the geometry is a Ψ-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent molecules are linked into a layer structure by N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2980214 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29802142010-12-30 μ-Adipato-κ(2) O (1):O (4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)} Wei, Lian-Qiang Zeng, Ming-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Ψ-octahedral coordination environment. When weaker Pb⋯O interactions are also considered, the geometry is a Ψ-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent molecules are linked into a layer structure by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980214/ /pubmed/21579952 http://dx.doi.org/10.1107/S1600536809052647 Text en © Wei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wei, Lian-Qiang Zeng, Ming-Hua Ng, Seik Weng μ-Adipato-κ(2) O (1):O (4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)} |
title | μ-Adipato-κ(2)
O
(1):O
(4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN
(3))pyridine-κN](nitrato-κO)lead(II)} |
title_full | μ-Adipato-κ(2)
O
(1):O
(4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN
(3))pyridine-κN](nitrato-κO)lead(II)} |
title_fullStr | μ-Adipato-κ(2)
O
(1):O
(4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN
(3))pyridine-κN](nitrato-κO)lead(II)} |
title_full_unstemmed | μ-Adipato-κ(2)
O
(1):O
(4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN
(3))pyridine-κN](nitrato-κO)lead(II)} |
title_short | μ-Adipato-κ(2)
O
(1):O
(4)-bis{[2,6-bis(1H-benzimidazol-2-yl-κN
(3))pyridine-κN](nitrato-κO)lead(II)} |
title_sort | μ-adipato-κ(2)
o
(1):o
(4)-bis{[2,6-bis(1h-benzimidazol-2-yl-κn
(3))pyridine-κn](nitrato-κo)lead(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980214/ https://www.ncbi.nlm.nih.gov/pubmed/21579952 http://dx.doi.org/10.1107/S1600536809052647 |
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