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μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}

The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl­ate group of the adipate unit by an...

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Detalles Bibliográficos
Autores principales: Wei, Lian-Qiang, Zeng, Ming-Hua, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980214/
https://www.ncbi.nlm.nih.gov/pubmed/21579952
http://dx.doi.org/10.1107/S1600536809052647
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author Wei, Lian-Qiang
Zeng, Ming-Hua
Ng, Seik Weng
author_facet Wei, Lian-Qiang
Zeng, Ming-Hua
Ng, Seik Weng
author_sort Wei, Lian-Qiang
collection PubMed
description The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl­ate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Ψ-octa­hedral coordination environment. When weaker Pb⋯O inter­actions are also considered, the geometry is a Ψ-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent mol­ecules are linked into a layer structure by N—H⋯O hydrogen bonds.
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spelling pubmed-29802142010-12-30 μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)} Wei, Lian-Qiang Zeng, Ming-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl­ate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Ψ-octa­hedral coordination environment. When weaker Pb⋯O inter­actions are also considered, the geometry is a Ψ-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent mol­ecules are linked into a layer structure by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980214/ /pubmed/21579952 http://dx.doi.org/10.1107/S1600536809052647 Text en © Wei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Lian-Qiang
Zeng, Ming-Hua
Ng, Seik Weng
μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title_full μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title_fullStr μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title_full_unstemmed μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title_short μ-Adipato-κ(2) O (1):O (4)-bis­{[2,6-bis­(1H-benzimidazol-2-yl-κN (3))pyridine-κN](nitrato-κO)lead(II)}
title_sort μ-adipato-κ(2) o (1):o (4)-bis­{[2,6-bis­(1h-benzimidazol-2-yl-κn (3))pyridine-κn](nitrato-κo)lead(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980214/
https://www.ncbi.nlm.nih.gov/pubmed/21579952
http://dx.doi.org/10.1107/S1600536809052647
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