Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]

The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene (bbtz) ligands and two O atoms from two symmetry-related mono...

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Detalles Bibliográficos
Autores principales: Zhu, Xia, Guo, Ying, Zou, Yun-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980217/
https://www.ncbi.nlm.nih.gov/pubmed/21579977
http://dx.doi.org/10.1107/S1600536809039415
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author Zhu, Xia
Guo, Ying
Zou, Yun-Ling
author_facet Zhu, Xia
Guo, Ying
Zou, Yun-Ling
author_sort Zhu, Xia
collection PubMed
description The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene (bbtz) ligands and two O atoms from two symmetry-related monodentate nitrate ligands in a distorted octa­hedral geometry. The Co atoms are bridged by four bbtz ligands, forming a two-dimensional (4,4) network parallel to (102).
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spelling pubmed-29802172010-12-30 Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)] Zhu, Xia Guo, Ying Zou, Yun-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene (bbtz) ligands and two O atoms from two symmetry-related monodentate nitrate ligands in a distorted octa­hedral geometry. The Co atoms are bridged by four bbtz ligands, forming a two-dimensional (4,4) network parallel to (102). International Union of Crystallography 2009-12-19 /pmc/articles/PMC2980217/ /pubmed/21579977 http://dx.doi.org/10.1107/S1600536809039415 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xia
Guo, Ying
Zou, Yun-Ling
Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title_full Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title_fullStr Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title_full_unstemmed Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title_short Poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) N (4):N (4′)]bis(nitrito-κO)cobalt(II)]
title_sort poly[bis­[μ(2)-1,4-bis­(1,2,4-triazol-1-yl­meth­yl)benzene-κ(2) n (4):n (4′)]bis(nitrito-κo)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980217/
https://www.ncbi.nlm.nih.gov/pubmed/21579977
http://dx.doi.org/10.1107/S1600536809039415
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AT zouyunling polybism214bis124triazol1ylmethylbenzenek2n4n4bisnitritokocobaltii

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