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1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate
In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980219/ https://www.ncbi.nlm.nih.gov/pubmed/21580166 http://dx.doi.org/10.1107/S1600536809051824 |
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author | Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. |
author_facet | Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. |
author_sort | Johnson, Samuel |
collection | PubMed |
description | In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and N(+)—H⋯O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C—H⋯O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H⋯π contacts. |
format | Text |
id | pubmed-2980219 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29802192010-12-30 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and N(+)—H⋯O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C—H⋯O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H⋯π contacts. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980219/ /pubmed/21580166 http://dx.doi.org/10.1107/S1600536809051824 Text en © Johnson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title | 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title_full | 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title_fullStr | 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title_full_unstemmed | 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title_short | 1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
title_sort | 1,12-bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980219/ https://www.ncbi.nlm.nih.gov/pubmed/21580166 http://dx.doi.org/10.1107/S1600536809051824 |
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