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1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate

In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and...

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Detalles Bibliográficos
Autores principales: Johnson, Samuel, Musie, Ghezai T., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980219/
https://www.ncbi.nlm.nih.gov/pubmed/21580166
http://dx.doi.org/10.1107/S1600536809051824
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author Johnson, Samuel
Musie, Ghezai T.
Tiekink, Edward R. T.
author_facet Johnson, Samuel
Musie, Ghezai T.
Tiekink, Edward R. T.
author_sort Johnson, Samuel
collection PubMed
description In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and N(+)—H⋯O charge-assisted hydrogen-bonding inter­actions. The assemblies thus formed are linked into supra­molecular helical chains along [010] via C—H⋯O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H⋯π contacts.
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spelling pubmed-29802192010-12-30 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate Johnson, Samuel Musie, Ghezai T. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt hydrate, C(22)H(30)N(2)O(6) (2+)·2Cl(−)·CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O—H⋯Cl(−), N(+)—H⋯Cl(−) and N(+)—H⋯O charge-assisted hydrogen-bonding inter­actions. The assemblies thus formed are linked into supra­molecular helical chains along [010] via C—H⋯O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C—H⋯π contacts. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980219/ /pubmed/21580166 http://dx.doi.org/10.1107/S1600536809051824 Text en © Johnson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Johnson, Samuel
Musie, Ghezai T.
Tiekink, Edward R. T.
1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title_full 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title_fullStr 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title_full_unstemmed 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title_short 1,12-Bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
title_sort 1,12-bis(2-carboxy­phen­yl)-5,8-dioxa-2,11-diaza­dodecane-2,11-diium dichloride methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980219/
https://www.ncbi.nlm.nih.gov/pubmed/21580166
http://dx.doi.org/10.1107/S1600536809051824
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