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(4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(dibenzoylmethanido-κ(2) O,O′)bis(nitrato-κ(2) O,O′)neodymium(III) acetonitrile solvate
The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980225/ https://www.ncbi.nlm.nih.gov/pubmed/21579918 http://dx.doi.org/10.1107/S160053680905185X |
| _version_ | 1782191607701831680 |
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| author | Mei, Qunbo Tong, Bihai |
| author_facet | Mei, Qunbo Tong, Bihai |
| author_sort | Mei, Qunbo |
| collection | PubMed |
| description | The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry. |
| format | Text |
| id | pubmed-2980225 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29802252010-12-30 (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(dibenzoylmethanido-κ(2) O,O′)bis(nitrato-κ(2) O,O′)neodymium(III) acetonitrile solvate Mei, Qunbo Tong, Bihai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4′-allyloxy-2,2′:6′,2′′-terpyridine, dbm = dibenzoylmethanide anion), has been synthesized from 4′-allyloxy-2,2′:6′,2′′-terpyridine, dibenzoylmethanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-antiprismatic geometry. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980225/ /pubmed/21579918 http://dx.doi.org/10.1107/S160053680905185X Text en © Mei and Tong 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mei, Qunbo Tong, Bihai (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(dibenzoylmethanido-κ(2) O,O′)bis(nitrato-κ(2) O,O′)neodymium(III) acetonitrile solvate |
| title | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(dibenzoylmethanido-κ(2)
O,O′)bis(nitrato-κ(2)
O,O′)neodymium(III) acetonitrile solvate |
| title_full | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(dibenzoylmethanido-κ(2)
O,O′)bis(nitrato-κ(2)
O,O′)neodymium(III) acetonitrile solvate |
| title_fullStr | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(dibenzoylmethanido-κ(2)
O,O′)bis(nitrato-κ(2)
O,O′)neodymium(III) acetonitrile solvate |
| title_full_unstemmed | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(dibenzoylmethanido-κ(2)
O,O′)bis(nitrato-κ(2)
O,O′)neodymium(III) acetonitrile solvate |
| title_short | (4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)(dibenzoylmethanido-κ(2)
O,O′)bis(nitrato-κ(2)
O,O′)neodymium(III) acetonitrile solvate |
| title_sort | (4′-allyloxy-2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)(dibenzoylmethanido-κ(2)
o,o′)bis(nitrato-κ(2)
o,o′)neodymium(iii) acetonitrile solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980225/ https://www.ncbi.nlm.nih.gov/pubmed/21579918 http://dx.doi.org/10.1107/S160053680905185X |
| work_keys_str_mv | AT meiqunbo 4allyloxy2262terpyridinek3nnndibenzoylmethanidok2oobisnitratok2ooneodymiumiiiacetonitrilesolvate AT tongbihai 4allyloxy2262terpyridinek3nnndibenzoylmethanidok2oobisnitratok2ooneodymiumiiiacetonitrilesolvate |