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Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride

The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl­enediamine ligands and two symmetry-related chl...

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Detalles Bibliográficos
Autores principales: Näther, Christian, Jess, Inke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980226/
https://www.ncbi.nlm.nih.gov/pubmed/21579987
http://dx.doi.org/10.1107/S1600536809054804
Descripción
Sumario:The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl­enediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octa­hedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N—H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethyl­enediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)].