Cargando…

Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride

The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl­enediamine ligands and two symmetry-related chl...

Descripción completa

Detalles Bibliográficos
Autores principales: Näther, Christian, Jess, Inke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980226/
https://www.ncbi.nlm.nih.gov/pubmed/21579987
http://dx.doi.org/10.1107/S1600536809054804
_version_ 1782191607929372672
author Näther, Christian
Jess, Inke
author_facet Näther, Christian
Jess, Inke
author_sort Näther, Christian
collection PubMed
description The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl­enediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octa­hedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N—H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethyl­enediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)].
format Text
id pubmed-2980226
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29802262010-12-30 Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl­enediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octa­hedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N—H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethyl­enediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)]. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980226/ /pubmed/21579987 http://dx.doi.org/10.1107/S1600536809054804 Text en © Näther and Jess 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Näther, Christian
Jess, Inke
Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title_full Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title_fullStr Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title_full_unstemmed Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title_short Di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) N,N′)cadmium(II)] dichloride
title_sort di-μ-chlorido-bis­[bis­(ethyl­enediamine-κ(2) n,n′)cadmium(ii)] dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980226/
https://www.ncbi.nlm.nih.gov/pubmed/21579987
http://dx.doi.org/10.1107/S1600536809054804
work_keys_str_mv AT natherchristian dimchloridobisbisethylenediaminek2nncadmiumiidichloride
AT jessinke dimchloridobisbisethylenediaminek2nncadmiumiidichloride