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Di-μ-chlorido-bis[bis(ethylenediamine-κ(2) N,N′)cadmium(II)] dichloride
The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethylenediamine ligands and two symmetry-related chl...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980226/ https://www.ncbi.nlm.nih.gov/pubmed/21579987 http://dx.doi.org/10.1107/S1600536809054804 |
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author | Näther, Christian Jess, Inke |
author_facet | Näther, Christian Jess, Inke |
author_sort | Näther, Christian |
collection | PubMed |
description | The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethylenediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octahedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N—H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethylenediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)]. |
format | Text |
id | pubmed-2980226 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29802262010-12-30 Di-μ-chlorido-bis[bis(ethylenediamine-κ(2) N,N′)cadmium(II)] dichloride Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethylenediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octahedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N—H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethylenediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)]. International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980226/ /pubmed/21579987 http://dx.doi.org/10.1107/S1600536809054804 Text en © Näther and Jess 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Näther, Christian Jess, Inke Di-μ-chlorido-bis[bis(ethylenediamine-κ(2) N,N′)cadmium(II)] dichloride |
title | Di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
N,N′)cadmium(II)] dichloride |
title_full | Di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
N,N′)cadmium(II)] dichloride |
title_fullStr | Di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
N,N′)cadmium(II)] dichloride |
title_full_unstemmed | Di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
N,N′)cadmium(II)] dichloride |
title_short | Di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
N,N′)cadmium(II)] dichloride |
title_sort | di-μ-chlorido-bis[bis(ethylenediamine-κ(2)
n,n′)cadmium(ii)] dichloride |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980226/ https://www.ncbi.nlm.nih.gov/pubmed/21579987 http://dx.doi.org/10.1107/S1600536809054804 |
work_keys_str_mv | AT natherchristian dimchloridobisbisethylenediaminek2nncadmiumiidichloride AT jessinke dimchloridobisbisethylenediaminek2nncadmiumiidichloride |