Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)

In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and...

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Detalles Bibliográficos
Autores principales: Wang, Cui-Juan, Zhou, Xian-Li, Zhang, Bing-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980230/
https://www.ncbi.nlm.nih.gov/pubmed/21579948
http://dx.doi.org/10.1107/S1600536809052659
Descripción
Sumario:In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and π–π inter­actions [centroid–centroid separation = 3.5535 (13) Å] link the mol­ecules into chains.

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