Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)

In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and...

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Detalles Bibliográficos
Autores principales: Wang, Cui-Juan, Zhou, Xian-Li, Zhang, Bing-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980230/
https://www.ncbi.nlm.nih.gov/pubmed/21579948
http://dx.doi.org/10.1107/S1600536809052659
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author Wang, Cui-Juan
Zhou, Xian-Li
Zhang, Bing-Jun
author_facet Wang, Cui-Juan
Zhou, Xian-Li
Zhang, Bing-Jun
author_sort Wang, Cui-Juan
collection PubMed
description In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and π–π inter­actions [centroid–centroid separation = 3.5535 (13) Å] link the mol­ecules into chains.
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spelling pubmed-29802302010-12-30 Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III) Wang, Cui-Juan Zhou, Xian-Li Zhang, Bing-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa­hedral geometry arising from the O,N,N′,O′-tetra­dentate Schiff base ligand, an azide ion and a water mol­ecule. In the crystal, inter­molecular O—H⋯(O,O) and O—H⋯N hydrogen bonds and π–π inter­actions [centroid–centroid separation = 3.5535 (13) Å] link the mol­ecules into chains. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980230/ /pubmed/21579948 http://dx.doi.org/10.1107/S1600536809052659 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Cui-Juan
Zhou, Xian-Li
Zhang, Bing-Jun
Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title_full Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title_fullStr Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title_full_unstemmed Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title_short Aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(III)
title_sort aqua­azido­{3,3′-[o-phenyl­enebis(nitrilo­methyl­idyne)]di-2-naphtholato}manganese(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980230/
https://www.ncbi.nlm.nih.gov/pubmed/21579948
http://dx.doi.org/10.1107/S1600536809052659
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