catena-Poly[[(liriodenine-κ(2) N,O)lead(II)]-di-μ-chlorido]

The title compound, [PbCl(2)(C(17)H(9)NO(3))](n), was synthesized by the hydro­thermal reaction of PbCl(2) and liriodenine. The lead(II) atom has a distorted octa­hedral environment made up of the O and N atoms of the liriodenine ligand [Pb—O 2.666 (4) Å, Pb—N 2.587 (5) Å, O—Pb—N 61.78 (14)°] and fo...

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Detalles Bibliográficos
Autores principales: Qin, Yan-Tao, Tao, Lu, He, Tian-Jing, Liu, Yan-Cheng, Chen, Zhen-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980232/
https://www.ncbi.nlm.nih.gov/pubmed/21579928
http://dx.doi.org/10.1107/S1600536809051381
Descripción
Sumario:The title compound, [PbCl(2)(C(17)H(9)NO(3))](n), was synthesized by the hydro­thermal reaction of PbCl(2) and liriodenine. The lead(II) atom has a distorted octa­hedral environment made up of the O and N atoms of the liriodenine ligand [Pb—O 2.666 (4) Å, Pb—N 2.587 (5) Å, O—Pb—N 61.78 (14)°] and four bridging chloro ligands, which link the complex mol­ecules into infinite chains along the a axis. Both crystallographically independent chloro-bridges are asymmetric, so that the Pb atom participates in two short [2.6872 (18) and 2.7952 (18) Å] and two noticeably longer Pb—Cl bonds [2.9626 (18) and 3.031 (2) Å].

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