1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene

The title compound, enmenol, C(20)H(30)O(6), a natural ent-kaurane diterpenoid, comprises five fused rings, four of which are six-membered. Cyclo­hexane ring A adopts a chair conformation, rings B and C adopt boat conformations, while ring D has an envelope conformation, and two intramolecular O—H⋯O...

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Detalles Bibliográficos
Autores principales: Feng, Chuang, Yan, Fu-Lin, Di, Xue-Mei, Sun, Peng-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980239/
https://www.ncbi.nlm.nih.gov/pubmed/21579994
http://dx.doi.org/10.1107/S1600536809052490
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author Feng, Chuang
Yan, Fu-Lin
Di, Xue-Mei
Sun, Peng-Li
author_facet Feng, Chuang
Yan, Fu-Lin
Di, Xue-Mei
Sun, Peng-Li
author_sort Feng, Chuang
collection PubMed
description The title compound, enmenol, C(20)H(30)O(6), a natural ent-kaurane diterpenoid, comprises five fused rings, four of which are six-membered. Cyclo­hexane ring A adopts a chair conformation, rings B and C adopt boat conformations, while ring D has an envelope conformation, and two intramolecular O—H⋯O interactions occur. In the crystal, inter­molecular O—H⋯O hydrogen bonds generate a two dimensional network.
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spelling pubmed-29802392010-12-30 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene Feng, Chuang Yan, Fu-Lin Di, Xue-Mei Sun, Peng-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, enmenol, C(20)H(30)O(6), a natural ent-kaurane diterpenoid, comprises five fused rings, four of which are six-membered. Cyclo­hexane ring A adopts a chair conformation, rings B and C adopt boat conformations, while ring D has an envelope conformation, and two intramolecular O—H⋯O interactions occur. In the crystal, inter­molecular O—H⋯O hydrogen bonds generate a two dimensional network. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980239/ /pubmed/21579994 http://dx.doi.org/10.1107/S1600536809052490 Text en © Feng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Feng, Chuang
Yan, Fu-Lin
Di, Xue-Mei
Sun, Peng-Li
1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title_full 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title_fullStr 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title_full_unstemmed 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title_short 1α,6β,7β,14β,15β-Penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
title_sort 1α,6β,7β,14β,15β-penta­hydr­oxy-7α,20-ep­oxy-ent-kaur-16-ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980239/
https://www.ncbi.nlm.nih.gov/pubmed/21579994
http://dx.doi.org/10.1107/S1600536809052490
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