catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]

In the title compound, [Zn(N(3))(2)(C(10)H(9)N(3))](n), tetra­hedrally coordinated Zn(II) ions with two monodentate azide ligands are linked into zigzag one-dimensional chain motifs by di-4-pyridylamine (dpa) tethers. Individual [Zn(N(3))(2)(dpa)](n) chains are connected into supra­molecular layers...

Descripción completa

Detalles Bibliográficos
Autores principales: Hardy, Aaron M., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980247/
https://www.ncbi.nlm.nih.gov/pubmed/21579920
http://dx.doi.org/10.1107/S1600536809051599
_version_ 1782191612995043328
author Hardy, Aaron M.
LaDuca, Robert L.
author_facet Hardy, Aaron M.
LaDuca, Robert L.
author_sort Hardy, Aaron M.
collection PubMed
description In the title compound, [Zn(N(3))(2)(C(10)H(9)N(3))](n), tetra­hedrally coordinated Zn(II) ions with two monodentate azide ligands are linked into zigzag one-dimensional chain motifs by di-4-pyridylamine (dpa) tethers. Individual [Zn(N(3))(2)(dpa)](n) chains are connected into supra­molecular layers via N—H⋯N hydrogen bonding between the central amine groups of the dpa ligands and terminal unligated azide N atoms. The azide ligands in one supra­molecular layer penetrate through the neighboring layers above and below, allowing stacking into a three-dimensional structure.
format Text
id pubmed-2980247
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29802472010-12-30 catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′] Hardy, Aaron M. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(N(3))(2)(C(10)H(9)N(3))](n), tetra­hedrally coordinated Zn(II) ions with two monodentate azide ligands are linked into zigzag one-dimensional chain motifs by di-4-pyridylamine (dpa) tethers. Individual [Zn(N(3))(2)(dpa)](n) chains are connected into supra­molecular layers via N—H⋯N hydrogen bonding between the central amine groups of the dpa ligands and terminal unligated azide N atoms. The azide ligands in one supra­molecular layer penetrate through the neighboring layers above and below, allowing stacking into a three-dimensional structure. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980247/ /pubmed/21579920 http://dx.doi.org/10.1107/S1600536809051599 Text en © Hardy and LaDuca 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hardy, Aaron M.
LaDuca, Robert L.
catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title_full catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title_fullStr catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title_short catena-Poly[[diazido­zinc(II)]-μ-di-4-pyridylamine-κ(2) N:N′]
title_sort catena-poly[[diazido­zinc(ii)]-μ-di-4-pyridylamine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980247/
https://www.ncbi.nlm.nih.gov/pubmed/21579920
http://dx.doi.org/10.1107/S1600536809051599
work_keys_str_mv AT hardyaaronm catenapolydiazidozinciimdi4pyridylaminek2nn
AT laducarobertl catenapolydiazidozinciimdi4pyridylaminek2nn

Ejemplares similares