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1-Benzyl-3-methylimidazolium chloride 0.25-hydrate
The asymmetric unit of the title compound, C(11)H(13)N(2) (+)·Cl(−), contains two independent ion pairs and and half a solvent water molecule (m site symmetry for the O atom). The imidazole ring is oriented at dihedral angles of 66.61 (3) and 89.17 (3)° with respect to the aromatic ring in the two...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980248/ https://www.ncbi.nlm.nih.gov/pubmed/21580102 http://dx.doi.org/10.1107/S1600536809053306 |
| Sumario: | The asymmetric unit of the title compound, C(11)H(13)N(2) (+)·Cl(−), contains two independent ion pairs and and half a solvent water molecule (m site symmetry for the O atom). The imidazole ring is oriented at dihedral angles of 66.61 (3) and 89.17 (3)° with respect to the aromatic ring in the two cations. In the crystal, O—H⋯(O,Cl) hydrogen bonds and π–π stacking interactions between the imidazole ring of one molecule and the aromatic ring of another [perpendicular distance = 3.4 (4) Å] link the molecules. |
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