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Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate
In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coordinated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolate ligand. The Na(I) ion is hexacoo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980255/ https://www.ncbi.nlm.nih.gov/pubmed/21579943 http://dx.doi.org/10.1107/S1600536809051150 |
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author | Ma, Xiao-Jian |
author_facet | Ma, Xiao-Jian |
author_sort | Ma, Xiao-Jian |
collection | PubMed |
description | In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coordinated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolate ligand. The Na(I) ion is hexacoordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water molecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms. |
format | Text |
id | pubmed-2980255 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29802552010-12-30 Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate Ma, Xiao-Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coordinated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolate ligand. The Na(I) ion is hexacoordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water molecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980255/ /pubmed/21579943 http://dx.doi.org/10.1107/S1600536809051150 Text en © Xiao-Jian Ma 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Xiao-Jian Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title | Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title_full | Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title_fullStr | Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title_full_unstemmed | Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title_short | Aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I) N,N-dimethylformamide solvate |
title_sort | aquachlorido{μ-6,6′-diethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato}copper(ii)sodium(i) n,n-dimethylformamide solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980255/ https://www.ncbi.nlm.nih.gov/pubmed/21579943 http://dx.doi.org/10.1107/S1600536809051150 |
work_keys_str_mv | AT maxiaojian aquachloridom66diethoxy2212phenylenebisnitrilomethylidynediphenolatocopperiisodiuminndimethylformamidesolvate |