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Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate

In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord­inated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­­idyne)]diphenolate ligand. The Na(I) ion is hexa­coo...

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Autor principal: Ma, Xiao-Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980255/
https://www.ncbi.nlm.nih.gov/pubmed/21579943
http://dx.doi.org/10.1107/S1600536809051150
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author Ma, Xiao-Jian
author_facet Ma, Xiao-Jian
author_sort Ma, Xiao-Jian
collection PubMed
description In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord­inated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­­idyne)]diphenolate ligand. The Na(I) ion is hexa­coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol­ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms.
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spelling pubmed-29802552010-12-30 Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate Ma, Xiao-Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord­inated in a square-planar geometry by two N atoms and two O atoms of the 6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­­idyne)]diphenolate ligand. The Na(I) ion is hexa­coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol­ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980255/ /pubmed/21579943 http://dx.doi.org/10.1107/S1600536809051150 Text en © Xiao-Jian Ma 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Xiao-Jian
Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title_full Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title_fullStr Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title_full_unstemmed Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title_short Aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl­formamide solvate
title_sort aqua­chlorido{μ-6,6′-dieth­oxy-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato}copper(ii)sodium(i) n,n-dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980255/
https://www.ncbi.nlm.nih.gov/pubmed/21579943
http://dx.doi.org/10.1107/S1600536809051150
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