Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)

The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro­acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa­hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(−) ion i...

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Detalles Bibliográficos
Autores principales: Pei, Changgui, Bai, Peikang, Guo, Zhangxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980258/
https://www.ncbi.nlm.nih.gov/pubmed/21579911
http://dx.doi.org/10.1107/S1600536809054671
Descripción
Sumario:The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro­acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa­hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(−) ion in the equatorial plane and one O atom from the trichloro­acetate ligand and one phenanthroline N atom in axial positions. This compound is isostructural with the analogous Mn(II) complex. The trichloro­methyl group of the trichloro­acetate ligand is disordered over two positions with occupancies of 0.190 (5) and 0.810 (5).

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