Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)

The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro­acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa­hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(−) ion i...

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Detalles Bibliográficos
Autores principales: Pei, Changgui, Bai, Peikang, Guo, Zhangxia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980258/
https://www.ncbi.nlm.nih.gov/pubmed/21579911
http://dx.doi.org/10.1107/S1600536809054671
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author Pei, Changgui
Bai, Peikang
Guo, Zhangxia
author_facet Pei, Changgui
Bai, Peikang
Guo, Zhangxia
author_sort Pei, Changgui
collection PubMed
description The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro­acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa­hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(−) ion in the equatorial plane and one O atom from the trichloro­acetate ligand and one phenanthroline N atom in axial positions. This compound is isostructural with the analogous Mn(II) complex. The trichloro­methyl group of the trichloro­acetate ligand is disordered over two positions with occupancies of 0.190 (5) and 0.810 (5).
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spelling pubmed-29802582010-12-30 Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II) Pei, Changgui Bai, Peikang Guo, Zhangxia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro­acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa­hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(−) ion in the equatorial plane and one O atom from the trichloro­acetate ligand and one phenanthroline N atom in axial positions. This compound is isostructural with the analogous Mn(II) complex. The trichloro­methyl group of the trichloro­acetate ligand is disordered over two positions with occupancies of 0.190 (5) and 0.810 (5). International Union of Crystallography 2009-12-24 /pmc/articles/PMC2980258/ /pubmed/21579911 http://dx.doi.org/10.1107/S1600536809054671 Text en © Pei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pei, Changgui
Bai, Peikang
Guo, Zhangxia
Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title_full Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title_fullStr Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title_full_unstemmed Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title_short Chloridobis(1,10-phenanthroline-κ(2) N,N′)(2,2,2-trichloro­acetato-κO)cobalt(II)
title_sort chloridobis(1,10-phenanthroline-κ(2) n,n′)(2,2,2-trichloro­acetato-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980258/
https://www.ncbi.nlm.nih.gov/pubmed/21579911
http://dx.doi.org/10.1107/S1600536809054671
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AT baipeikang chloridobis110phenanthrolinek2nn222trichloroacetatokocobaltii
AT guozhangxia chloridobis110phenanthrolinek2nn222trichloroacetatokocobaltii

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