2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione

In the title compound, C(25)H(28)NO(2)PS, the cyclo­decene ring exhibits a crown conformation. The two dimethyl­benzene rings which are fused symmetrically on either side of the ten-membered ring, make dihedral angles of 20.2 (1) and 18.0 (1)°. The phenyl ring substituted at P is perpendicular to th...

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Detalles Bibliográficos
Autores principales: Krishnaiah, M., Babu, V.H.H. Surendra, Sankar, A. Uma Ravi, Raju, C. Naga, Kant, Rajni
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980263/
https://www.ncbi.nlm.nih.gov/pubmed/21580010
http://dx.doi.org/10.1107/S1600536809052180
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author Krishnaiah, M.
Babu, V.H.H. Surendra
Sankar, A. Uma Ravi
Raju, C. Naga
Kant, Rajni
author_facet Krishnaiah, M.
Babu, V.H.H. Surendra
Sankar, A. Uma Ravi
Raju, C. Naga
Kant, Rajni
author_sort Krishnaiah, M.
collection PubMed
description In the title compound, C(25)H(28)NO(2)PS, the cyclo­decene ring exhibits a crown conformation. The two dimethyl­benzene rings which are fused symmetrically on either side of the ten-membered ring, make dihedral angles of 20.2 (1) and 18.0 (1)°. The phenyl ring substituted at P is perpendicular to the heterocyclic ring, making a dihedral angle of 88.4 (1)°. The crystal structure is stabilized by very weak intra­molecular C—H⋯O hydrogen bonding.
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spelling pubmed-29802632010-12-30 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione Krishnaiah, M. Babu, V.H.H. Surendra Sankar, A. Uma Ravi Raju, C. Naga Kant, Rajni Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(28)NO(2)PS, the cyclo­decene ring exhibits a crown conformation. The two dimethyl­benzene rings which are fused symmetrically on either side of the ten-membered ring, make dihedral angles of 20.2 (1) and 18.0 (1)°. The phenyl ring substituted at P is perpendicular to the heterocyclic ring, making a dihedral angle of 88.4 (1)°. The crystal structure is stabilized by very weak intra­molecular C—H⋯O hydrogen bonding. International Union of Crystallography 2009-12-12 /pmc/articles/PMC2980263/ /pubmed/21580010 http://dx.doi.org/10.1107/S1600536809052180 Text en © Krishnaiah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Krishnaiah, M.
Babu, V.H.H. Surendra
Sankar, A. Uma Ravi
Raju, C. Naga
Kant, Rajni
2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title_full 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title_fullStr 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title_full_unstemmed 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title_short 2,4,8,10,13-Penta­methyl-6-phenyl-13,14-dihydro-12H-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
title_sort 2,4,8,10,13-penta­methyl-6-phenyl-13,14-dihydro-12h-6λ(5)-dibenzo[d,i][1,3,7,2]dioxaza­phosphecin-6-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980263/
https://www.ncbi.nlm.nih.gov/pubmed/21580010
http://dx.doi.org/10.1107/S1600536809052180
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