2-Methyl-N-o-tolyl­benzamide

In the title compound, C(15)H(15)NO, the C—N—C(O)—C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Khera, Rasheed Ahmad, Siddiq, Muhammad, Simpson, Jim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980266/
https://www.ncbi.nlm.nih.gov/pubmed/21580074
http://dx.doi.org/10.1107/S1600536809050946
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author Saeed, Aamer
Khera, Rasheed Ahmad
Siddiq, Muhammad
Simpson, Jim
author_facet Saeed, Aamer
Khera, Rasheed Ahmad
Siddiq, Muhammad
Simpson, Jim
author_sort Saeed, Aamer
collection PubMed
description In the title compound, C(15)H(15)NO, the C—N—C(O)—C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N—H⋯O hydrogen bonds augmented by C—H⋯π inter­actions link the mol­ecules in a head-to-head fashion into chains along a. Independent chains pack in a herringbone pattern along c.
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spelling pubmed-29802662010-12-30 2-Methyl-N-o-tolyl­benzamide Saeed, Aamer Khera, Rasheed Ahmad Siddiq, Muhammad Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)NO, the C—N—C(O)—C amide unit is planar (r.m.s. deviation = 0.003 Å) and subtends dihedral angles of 44.71 (5) and 43.33 (5)° with the two o-tolyl rings. These aromatic rings are inclined at 4.94 (7)° to one another. The ortho-methyl groups of the two tolyl rings are anti to one another. In the crystal structure, N—H⋯O hydrogen bonds augmented by C—H⋯π inter­actions link the mol­ecules in a head-to-head fashion into chains along a. Independent chains pack in a herringbone pattern along c. International Union of Crystallography 2009-12-04 /pmc/articles/PMC2980266/ /pubmed/21580074 http://dx.doi.org/10.1107/S1600536809050946 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Khera, Rasheed Ahmad
Siddiq, Muhammad
Simpson, Jim
2-Methyl-N-o-tolyl­benzamide
title 2-Methyl-N-o-tolyl­benzamide
title_full 2-Methyl-N-o-tolyl­benzamide
title_fullStr 2-Methyl-N-o-tolyl­benzamide
title_full_unstemmed 2-Methyl-N-o-tolyl­benzamide
title_short 2-Methyl-N-o-tolyl­benzamide
title_sort 2-methyl-n-o-tolyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2980266/
https://www.ncbi.nlm.nih.gov/pubmed/21580074
http://dx.doi.org/10.1107/S1600536809050946
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AT siddiqmuhammad 2methylnotolylbenzamide
AT simpsonjim 2methylnotolylbenzamide

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